{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:18Z","timestamp":1736831838620,"version":"3.33.0"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T00:00:00Z","timestamp":1440547200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T00:00:00Z","timestamp":1440547200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,9,1]]},"abstract":"<jats:p>The title compound, [CrCu(C<jats:sub>5<\/jats:sub>H<jats:sub>11<\/jats:sub>NO<jats:sub>2<\/jats:sub>)(C<jats:sub>5<\/jats:sub>H<jats:sub>12<\/jats:sub>NO<jats:sub>2<\/jats:sub>)(NCS)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)] or [Cr(\u03bc-mdea)Cu(\u03bc-Hmdea)(NCS)<jats:sub>2<\/jats:sub>H<jats:sub>2<\/jats:sub>O], (where mdeaH<jats:sub>2<\/jats:sub>is<jats:italic>N<\/jats:italic>-methylethanolamine, C<jats:sub>5<\/jats:sub>H<jats:sub>13<\/jats:sub>NO<jats:sub>2<\/jats:sub>) is formed as a neutral heterometal Cu<jats:sup>II<\/jats:sup>\/Cr<jats:sup>III<\/jats:sup>complex. The molecular structure of the complex is based on a binuclear {CuCr(\u03bc-O)<jats:sub>2<\/jats:sub>} core. The coordination environment of each metal atom involves the<jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>atoms of the tridentate ligand, one bridging O atom of the ligand and the N atom of the thiocyanato ligands. The Cu<jats:sup>II<\/jats:sup>ion adopts a distorted square-pyramidal coordination while the Cr<jats:sup>III<\/jats:sup>ion has a distorted octahedral coordination geometry completed by the aqua ligand. In the crystal, the binuclear complexes are linked<jats:italic>via<\/jats:italic>two pairs of O\u2014H...O hydrogen bonds to form inversion dimers, which are arranged in columns parallel to the<jats:italic>a<\/jats:italic>axis. In the \u03bc-mdea ligand two \u2013CH<jats:sub>2<\/jats:sub>groups and the methyl group were refined as disordered over two sets of sites with equal occupancies. The structure was refined as a two-component twin with a twin scale factor of 0.242\u2005(1).<\/jats:p>","DOI":"10.1107\/s2056989015015601","type":"journal-article","created":{"date-parts":[[2015,8,25]],"date-time":"2015-08-25T09:10:53Z","timestamp":1440493853000},"page":"1077-1080","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of aqua-1\u03ba<i>O<\/i>-{\u03bc-2-[(2-hydroxyethyl)methylamino]ethanolato-2:1\u03ba<sup>4<\/sup><i>O<\/i><sup>1<\/sup>,<i>N<\/i>,<i>O<\/i><sup>2<\/sup>:<i>O<\/i><sup>1<\/sup>}[\u03bc-2,2\u2032-(methylimino)diethanolato-1:2\u03ba<sup>4<\/sup><i>O<\/i>,<i>N<\/i>,<i>O<\/i>\u2032:<i>O<\/i>]dithiocyanato-1\u03ba<i>N<\/i>,2\u03ba<i>N<\/i>-chromium(III)copper(II)"],"prefix":"10.1107","volume":"71","author":[{"given":"Julia A.","family":"Rusanova","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Valentina V.","family":"Semenaka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Viktoriya V.","family":"Dyakonenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oleg V.","family":"Shishkin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,8,26]]},"reference":[{"key":"lh5774_bb1","doi-asserted-by":"crossref","first-page":"6496","DOI":"10.1002\/anie.200502505","volume":"44","author":"Affronte","year":"2005","journal-title":"Angew. 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