{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:58Z","timestamp":1736831878236,"version":"3.33.0"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2015,9,12]],"date-time":"2015-09-12T00:00:00Z","timestamp":1442016000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,9,12]],"date-time":"2015-09-12T00:00:00Z","timestamp":1442016000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,10,1]]},"abstract":"<jats:p>In the unit cell of the title compound, (C<jats:sub>21<\/jats:sub>H<jats:sub>27<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>[CoBr<jats:sub>4<\/jats:sub>]Br\u00b76CHCl<jats:sub>3<\/jats:sub>, the tetrabromidocobaltate(II) anion and the bromide anion are located on a crystallographic threefold rotation axis. For the [CoBr<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>group, the axis runs through one of the Br ligands and the Co<jats:sup>II<\/jats:sup>atom. All other structure moieties lie on general sites. Various tris(1,3-dimesityl-4,5-dihydro-1<jats:italic>H<\/jats:italic>-imidazol-3-ium) structures with different counter-ions have been reported. In the title compound, the N\u2014C\u2014N angle is 113.7\u2005(5)\u00b0, with short C\u2014N bond lengths of 1.297\u2005(7) and 1.307\u2005(7)\u2005\u00c5. The two mesityl planes make a dihedral angle of 34.6\u2005(1)\u00b0 and the dihedral angles between the mesityl and N\u2013C\u2013N planes are 82.0\u2005(1) and 88.5\u2005(1)\u00b0, respectively. The imidazoline ring is almost planar, with atom deviations in the range 0.003\u2005(5)\u20130.017\u2005(5)\u2005\u00c5 from the best plane; the mean deviation is 0.012\u2005(5)\u2005\u00c5. In the crystal, non-covalent interactions of the C\u2014H...Br type occur between the Br<jats:sup>\u2212<\/jats:sup>anion and the cation, as well as between the [CoBr<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anion and both the chloroform solvent molecules. These H...<jats:italic>A<\/jats:italic>distances are slightly shorter than the sum of van der Waals radii.<\/jats:p>","DOI":"10.1107\/s2056989015016254","type":"journal-article","created":{"date-parts":[[2015,9,22]],"date-time":"2015-09-22T19:25:42Z","timestamp":1442949942000},"page":"m177-m178","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of tris(1,3-dimesityl-4,5-dihydro-1<i>H<\/i>-imidazol-3-ium) tetrabromidocobaltate(II) bromide chloroform hexasolvate"],"prefix":"10.1107","volume":"71","author":[{"given":"Eduard","family":"Rais","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ulrich","family":"Fl\u00f6rke","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ren\u00e9","family":"Wilhelm","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,9,12]]},"reference":[{"key":"nr2061_bb1","doi-asserted-by":"crossref","first-page":"11027","DOI":"10.1021\/ja00149a034","volume":"117","author":"Arduengo","year":"1995","journal-title":"J. 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Sci."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/10\/00\/nr2061\/nr2061.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/10\/00\/nr2061\/nr2061.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:48:38Z","timestamp":1736765318000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989015016254"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,9,12]]},"references-count":13,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2015,10]]}},"alternative-id":["S2056989015016254"],"URL":"https:\/\/doi.org\/10.1107\/s2056989015016254","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2015,9,12]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"data reports","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"13 August 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"31 August 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 September 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?nr2061"}},{"value":"\u00a9 2015 Raiset al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}