{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T01:04:51Z","timestamp":1762045491662,"version":"3.33.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2015,9,30]],"date-time":"2015-09-30T00:00:00Z","timestamp":1443571200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,9,30]],"date-time":"2015-09-30T00:00:00Z","timestamp":1443571200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,10,1]]},"abstract":"<jats:p>In the title compound, [Na<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>9<\/jats:sub>](C<jats:sub>7<\/jats:sub>H<jats:sub>4<\/jats:sub>ClO<jats:sub>2<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>ClN<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>S) {systematic name:<jats:italic>catena<\/jats:italic>-poly[[[triaquasodium(I)]-di-\u03bc-aqua-[triaquasodium(I)]-\u03bc-aqua] 3-chlorobenzoate 4-chloro-2-[(furan-2-ylmethyl)amino]-5-sulfamoylbenzoate]}, both the original<jats:italic>m<\/jats:italic>-chlorobenzoic acid and furosemide exist with deprotonated carboxylates, and the sodium cations and water molecules exist in chains with stoichiometry [Na<jats:sub>2<\/jats:sub>(OH<jats:sub>2<\/jats:sub>)<jats:sub>9<\/jats:sub>]<jats:sup>2+<\/jats:sup>that propagate in the [-110] direction. Each of the two independent Na<jats:sup>+<\/jats:sup>ions is coordinated by three monodentate water molecules, two double-water bridges, and one single-water bridge. There is considerable cross-linking between the [Na<jats:sub>2<\/jats:sub>(OH<jats:sub>2<\/jats:sub>)<jats:sub>9<\/jats:sub>]<jats:sup>2+<\/jats:sup>chains and to furosemide sulfonamide and carboxylate by intermolecular O\u2014H...O hydrogen bonds. All hydrogen-bond donors participate in a complex two-dimensional array parallel to the<jats:italic>ab<\/jats:italic>plane. The furosemide NH group donates an intramolecular hydrogen bond to the carboxylate group, and the furosemide NH<jats:sub>2<\/jats:sub>group donates an intramolecular hydrogen bond to the Cl atom and an intermolecular one to the<jats:italic>m<\/jats:italic>-chlorobenzoate O atom. The plethora of hydrogen-bond donors on the cation\/water chain leads to many large rings, up to graph set<jats:italic>R<\/jats:italic><jats:sub>4<\/jats:sub><jats:sup>4<\/jats:sup>(24), involving two chains and two furosemide anions. The chlorobenzoate is involved in only one<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(8) ring, with two water molecules<jats:italic>cis<\/jats:italic>-coordinated to Na. The furan O atom is not hydrogen bonded.<\/jats:p>","DOI":"10.1107\/s2056989015017430","type":"journal-article","created":{"date-parts":[[2015,9,29]],"date-time":"2015-09-29T09:36:17Z","timestamp":1443519377000},"page":"1266-1269","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A co-crystal of nonahydrated disodium(II) with mixed anions from<i>m<\/i>-chlorobenzoic acid and furosemide"],"prefix":"10.1107","volume":"71","author":[{"given":"Bianca King","family":"London","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michelle O. 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