{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:18:33Z","timestamp":1736831913751,"version":"3.33.0"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2015,10,24]],"date-time":"2015-10-24T00:00:00Z","timestamp":1445644800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,10,24]],"date-time":"2015-10-24T00:00:00Z","timestamp":1445644800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,11,1]]},"abstract":"<jats:p>The title compound, [Hg<jats:sub>3<\/jats:sub>(C<jats:sub>6<\/jats:sub>F<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>]\u00b7C<jats:sub>6<\/jats:sub>N<jats:sub>4<\/jats:sub>, contains one molecule of tetracyanoethylene<jats:bold>B<\/jats:bold>per one molecule of mercury macrocycle<jats:bold>A<\/jats:bold>,<jats:italic>i.e.<\/jats:italic>,<jats:bold>A\u2022B<\/jats:bold>, and crystallizes in the monoclinic space group<jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>. Macrocycle<jats:bold>A<\/jats:bold>and molecule<jats:bold>B<\/jats:bold>both occupy special positions on a twofold rotation axis and the inversion centre, respectively. The supramolecular unit [<jats:bold>A\u2022B<\/jats:bold>] is built by the simultaneous coordination of one of the nitrile N atoms of<jats:bold>B<\/jats:bold>to the three mercury atoms of the macrocycle<jats:bold>A<\/jats:bold>. The Hg...N distances range from 2.990\u2005(4) to 3.030\u2005(4)\u2005\u00c5 and are very close to those observed in the related adducts of the macrocycle<jats:bold>A<\/jats:bold>with other nitrile derivatives. The molecule of<jats:bold>B<\/jats:bold>is almost perpendicular to the mean plane of the macrocycle<jats:bold>A<\/jats:bold>at the dihedral angle of 88.20\u2005(5)\u00b0. The donor\u2013acceptor Hg...N interactions do not affect the C[triple-bond]N bond lengths [1.136\u2005(6) and 1.140\u2005(6)\u2005\u00c5]. The<jats:italic>trans<\/jats:italic>nitrile group of<jats:bold>B<\/jats:bold>coordinates to another macrocycle<jats:bold>A<\/jats:bold>, forming an infinite mixed-stack [<jats:bold>A\u2022B<\/jats:bold>]<jats:sub>\u221e<\/jats:sub>architecture toward [101]. The remaining N atoms of two nitrile groups of<jats:bold>B<\/jats:bold>are not engaged in any donor\u2013acceptor interactions. In the crystal, the mixed stacks are held together by intermolecular C\u2014F...C[triple-bond]N secondary interactions [2.846\u2005(5)\u20132.925\u2005(5)\u2005\u00c5].<\/jats:p>","DOI":"10.1107\/s2056989015019350","type":"journal-article","created":{"date-parts":[[2015,10,24]],"date-time":"2015-10-24T13:34:09Z","timestamp":1445693649000},"page":"1375-1378","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of<i>cyclo<\/i>-tris(\u03bc-3,4,5,6-tetrafluoro-<i>o<\/i>-phenylene-\u03ba<sup>2<\/sup><i>C<\/i><sup>1<\/sup>:<i>C<\/i><sup>2<\/sup>)trimercury\u2013tetracyanoethylene (1\/1)"],"prefix":"10.1107","volume":"71","author":[{"given":"Ra\u00fal","family":"Casta\u00f1eda","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatiana V.","family":"Timofeeva","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Victor N.","family":"Khrustalev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,10,24]]},"reference":[{"unstructured":"Bruker (2001). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.","key":"ru2064_bb1"},{"unstructured":"Bruker (2003). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.","key":"ru2064_bb2"},{"unstructured":"Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.","key":"ru2064_bb3"},{"key":"ru2064_bb4","first-page":"9522","volume":"C111","author":"Elbjeirami","year":"2007","journal-title":"J. Phys. Chem."},{"key":"ru2064_bb5","doi-asserted-by":"crossref","first-page":"2877","DOI":"10.1016\/j.jorganchem.2011.01.038","volume":"696","author":"Filatov","year":"2011","journal-title":"J. Organomet. Chem."},{"key":"ru2064_bb6","doi-asserted-by":"crossref","first-page":"8473","DOI":"10.1002\/anie.200903427","volume":"48","author":"Filatov","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"key":"ru2064_bb7","doi-asserted-by":"crossref","first-page":"5471","DOI":"10.1002\/anie.200461152","volume":"43","author":"Haneline","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"ru2064_bb8","doi-asserted-by":"crossref","first-page":"871","DOI":"10.1016\/j.crci.2003.12.018","volume":"7","author":"Haneline","year":"2004","journal-title":"C. R. Chim."},{"key":"ru2064_bb9","doi-asserted-by":"crossref","first-page":"3737","DOI":"10.1021\/ja0166794","volume":"124","author":"Haneline","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ru2064_bb10","doi-asserted-by":"crossref","first-page":"245115","DOI":"10.1103\/PhysRevB.69.245115","volume":"69","author":"Hasegawa","year":"2004","journal-title":"Phys. Rev. B"},{"key":"ru2064_bb11","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1021\/am201506h","volume":"4","author":"Kao","year":"2012","journal-title":"Appl. Mater. Interfaces"},{"key":"ru2064_bb12","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1002\/cber.19681010615","volume":"101","author":"Sartori","year":"1968","journal-title":"Chem. Ber."},{"key":"ru2064_bb13","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"ru2064_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ru2064_bb15","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1007\/s10904-007-9183-7","volume":"18","author":"Taylor","year":"2008","journal-title":"J. Inorg. Organomet. Polym."},{"key":"ru2064_bb16","doi-asserted-by":"crossref","first-page":"2143","DOI":"10.1021\/om060186w","volume":"25","author":"Taylor","year":"2006","journal-title":"Organometallics"},{"key":"ru2064_bb17","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/S0022-328X(00)00506-4","volume":"613","author":"Tikhonova","year":"2000","journal-title":"J. Organomet. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/11\/00\/ru2064\/ru2064.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/11\/00\/ru2064\/ru2064.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:55:42Z","timestamp":1736765742000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989015019350"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,10,24]]},"references-count":17,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2015,11]]}},"alternative-id":["S2056989015019350"],"URL":"https:\/\/doi.org\/10.1107\/s2056989015019350","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2015,10,24]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"research communications","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"8 August 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 October 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 October 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ru2064"}},{"value":"\u00a9 2015 Casta\u00f1edaet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}