{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T09:19:25Z","timestamp":1758273565796,"version":"3.33.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2015,11,14]],"date-time":"2015-11-14T00:00:00Z","timestamp":1447459200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,11,14]],"date-time":"2015-11-14T00:00:00Z","timestamp":1447459200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,12,1]]},"abstract":"<jats:p>In the structure of the title compound, [CdCl<jats:sub>2<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub>], the Cd<jats:sup>II<\/jats:sup>atom is coordinated by two chloride ions and two 1,3-diazinane-2-thione (Diaz) molecules through their S atoms. The geometry around the Cd<jats:sup>II<\/jats:sup>atom is distorted tetrahedral, with bond angles in the range 101.55\u2005(7)\u2013117.91\u2005(8)\u00b0. The CH<jats:sub>2<\/jats:sub>groups of one Diaz ligand are disordered over two sets of sites with an occupancy ratio of 0.711\u2005(12):0.289\u2005(12). The molecular structure is stabilized by intramolecular N\u2014H...Cl hydrogen-bonding interactions, generating a butterfly<jats:italic>syn<\/jats:italic>conformation. Intermolecular N\u2014H...Cl and N\u2014H...S interactions lead to the formation of a three-dimensional network structure. The structure has been determined from a crystal twinned by nonmerohedry, by a 180\u00b0 rotation around the reciprocal<jats:italic>c<\/jats:italic>axis. 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