{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,3]],"date-time":"2026-04-03T16:40:15Z","timestamp":1775234415718,"version":"3.50.1"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2015,11,21]],"date-time":"2015-11-21T00:00:00Z","timestamp":1448064000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,11,21]],"date-time":"2015-11-21T00:00:00Z","timestamp":1448064000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,12,1]]},"abstract":"<jats:p>The reaction between the racemic mixture of the camphor-4-phenylthiosemicarbazone derivative and cadmium acetate dihydrate yielded the title compound, [Cd(C<jats:sub>17<\/jats:sub>H<jats:sub>20<\/jats:sub>N<jats:sub>3<\/jats:sub>OS)<jats:sub>2<\/jats:sub>]. The Cd<jats:sup>II<\/jats:sup>ion is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting as an<jats:italic>O,N,S<\/jats:italic>-donor in a tridentate chelating mode, forming five-membered chelate rings. In the crystal, the molecules are connected<jats:italic>via<\/jats:italic>pairs of N\u2014H...S and C\u2014H...S interactions, building centrosymmetric dimers. One of the ligands is disordered in the campher unit over two sets of sites with site-occupancy factors of 0.7 and 0.3. The structure contains additional solvent molecules, which are disordered and for which no reasonable split model was found. Therefore, the data were corrected for disordered solvent using the SQUEEZE routine [Spek (2015).<jats:italic>Acta Cryst.<\/jats:italic>C<jats:bold>71<\/jats:bold>, 9\u201318] in<jats:italic>PLATON<\/jats:italic>. Since the disordered solvents were removed by data processing, and the number of solvent entities was a suggestion only, they were not considered in the chemical formula and subsequent chemical or crystal information.<\/jats:p>","DOI":"10.1107\/s2056989015021428","type":"journal-article","created":{"date-parts":[[2015,11,20]],"date-time":"2015-11-20T11:52:13Z","timestamp":1448020333000},"page":"m234-m235","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of<i>cis<\/i>-bis{4-phenyl-1-[(3<i>R<\/i>)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]thiosemicarbazidato-\u03ba<sup>3<\/sup><i>O<\/i>,<i>N<\/i><sup>1<\/sup>,<i>S<\/i>}cadmium(II) with an unknown solvent molecule"],"prefix":"10.1107","volume":"71","author":[{"given":"Vanessa Senna","family":"Nogueira","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Leandro","family":"Bresolin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Adriano Bof de","family":"Oliveira","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,11,21]]},"reference":[{"key":"is5430_bb1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1107\/S0021889804003528","volume":"37","author":"Allen","year":"2004","journal-title":"J. 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