{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:44Z","timestamp":1736844584246,"version":"3.33.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2016,1,1]],"date-time":"2016-01-01T00:00:00Z","timestamp":1451606400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,1,1]],"date-time":"2016-01-01T00:00:00Z","timestamp":1451606400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,1,1]]},"abstract":"<jats:p>The title compound, (2,2\u2032-bipyridine-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032)triiodidomethyltin(IV), [Sn(CH<jats:sub>3<\/jats:sub>)I<jats:sub>3<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)], crystallizing in the non-centrosymmetric orthorhombic space group<jats:italic>Pca<\/jats:italic>2<jats:sub>1<\/jats:sub>as an inversion twin, represents one of the few structurally characterized coordination compounds of an organotin(IV) trihalide with 2,2\u2032-biypridine. Its distorted octahedral geometry shows a meridional arrangement of the I atoms and the methyl group is in-plane with the five-membered chelate ring. Asymmetric bonding of the biypridine ligand to the tin(IV) atom is reflected by different Sn\u2014N bond lengths [2.268\u2005(4)\u2005\u00c5<jats:italic>versus<\/jats:italic>2.293\u2005(4)\u2005\u00c5] and caused by the static<jats:italic>trans<\/jats:italic>effect of the methyl group. Sn\u2014I bond lengths show some differences with respect to their orientation to the methyl group or the bipyridine ligand, respectively. Angular distortions in the coordination sphere of the Sn<jats:sup>IV<\/jats:sup>atom mainly arise from the large I atoms. Distortion of the 2,2\u2032-bipyridine ligand as a result of its coordination to the Sn<jats:sup>IV<\/jats:sup>atom are described by the twisting angle of 2.5\u2005(2)\u00b0 between the least-squares planes of the two pyridine rings, as well as by the angle of 6.2\u2005(2)\u00b0 between the two lines through the pyridine-connecting C atoms and the<jats:italic>para<\/jats:italic>-orientated C atoms. Directional intermolecular interactions are restricted to weak I...H van der Waals contacts.<\/jats:p>","DOI":"10.1107\/s2056989015022975","type":"journal-article","created":{"date-parts":[[2015,12,3]],"date-time":"2015-12-03T16:25:10Z","timestamp":1449159910000},"page":"17-20","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of the coordination compound of triiodidomethyltin(IV) with 2,2\u2032-bipyridine, MeSnI<sub>3<\/sub>\u00b7bipy"],"prefix":"10.1107","volume":"72","author":[{"given":"Hans","family":"Reuter","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"Reichelt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,1,1]]},"reference":[{"key":"zl2654_bb1","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1016\/0022-328X(87)80199-7","volume":"327","author":"Amini","year":"1987","journal-title":"J. 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