{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:45Z","timestamp":1736844585215,"version":"3.33.0"},"reference-count":6,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2015,12,12]],"date-time":"2015-12-12T00:00:00Z","timestamp":1449878400000},"content-version":"vor","delay-in-days":11,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,12,12]],"date-time":"2015-12-12T00:00:00Z","timestamp":1449878400000},"content-version":"tdm","delay-in-days":11,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,12,1]]},"abstract":"<jats:p>In the structure of the binuclear title compound, [Cd<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>13<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>Cl<jats:sub>6<\/jats:sub>], two Cd<jats:sup>II<\/jats:sup>atoms are bridged by two Cl<jats:sup>\u2212<\/jats:sup>ligands, defining a centrosymmetric Cd<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>motif. Each metal cation is additionally coordinated by two Cl<jats:sup>\u2212<\/jats:sup>ligands and the N atom of a protonated 1,4-diazabicyclo[2.2.2]octane (H-DABCO)<jats:sup>+<\/jats:sup>ligand, leading to an overall trigonal\u2013bipyramidal coordination environment with one of the bridging Cl<jats:sup>\u2212<\/jats:sup>ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked<jats:italic>via<\/jats:italic>N\u2014H...Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100).<\/jats:p>","DOI":"10.1107\/s2056989015023361","type":"journal-article","created":{"date-parts":[[2015,12,13]],"date-time":"2015-12-13T05:07:14Z","timestamp":1449983234000},"page":"m259-m260","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of di-\u03bc<sub>2<\/sub>-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-\u03ba<i>N<\/i><sup>1<\/sup>)dichloridodicadmium]"],"prefix":"10.1107","volume":"71","author":[{"given":"Jing-Jing","family":"Yan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qi-Jian","family":"Pan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li-Zhuang","family":"Chen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,12,12]]},"reference":[{"key":"wm5244_bb1","unstructured":"Brandenburg, K. 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