{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:45Z","timestamp":1736844585681,"version":"3.33.0"},"reference-count":8,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2015,12,16]],"date-time":"2015-12-16T00:00:00Z","timestamp":1450224000000},"content-version":"vor","delay-in-days":15,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,12,16]],"date-time":"2015-12-16T00:00:00Z","timestamp":1450224000000},"content-version":"tdm","delay-in-days":15,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,12,1]]},"abstract":"<jats:p>The title compound, [SnBr<jats:sub>4<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>S<jats:sub>2<\/jats:sub>)] {systematic name:<jats:italic>catena<\/jats:italic>-poly[[tetrabromidotin(IV)]-\u03bc-1,4-dithiane-\u03ba<jats:sup>2<\/jats:sup><jats:italic>S<\/jats:italic>:<jats:italic>S<\/jats:italic>\u2032]}, represents the first 1,4-dithiane complex with tin as coordination centre. The asymmetric unit consist of half a formula unit with the tin(IV) atom at the centre of symmetry at 0,0,1\/2 (Wyckoff symbol<jats:italic>b<\/jats:italic>) and a centrosymmetric 1,4-dithiane molecule with the centre of symmetry in 1\/2,0,1 (Wyckoff symbol<jats:italic>c<\/jats:italic>). The tin(IV) atom is coordinated in a distorted octahedral manner by the four bromine atoms and two sulfur atoms of two 1,4-dithiane molecules in a<jats:italic>trans<\/jats:italic>-position. Sn\u2014Br [mean value: 2.561\u2005(5)\u2005\u00c5] and Sn\u2014S distances [2.6546\u2005(6)\u2005\u00c5] are in the typical range for octahedrally coordinated tin(IV) atoms and the dithiane molecule adopts a chair conformation. The one-dimensional polymeric chains propagate along the [101] direction with weak intermolecular Br...Br [3.5724\u2005(4)\u2005\u00c5] between parallel chains and weak Br...H interactions [2.944\u20132.993\u2005\u00c5] within the chains.<\/jats:p>","DOI":"10.1107\/s2056989015023932","type":"journal-article","created":{"date-parts":[[2015,12,16]],"date-time":"2015-12-16T13:04:29Z","timestamp":1450271069000},"page":"m267-m268","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a one-dimensional coordination polymer of tin(IV) bromide with 1,4-dithiane"],"prefix":"10.1107","volume":"71","author":[{"given":"Hans","family":"Reuter","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Natalia","family":"R\u00f6wekamp-Krugley","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marius","family":"Imwalle","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Simona","family":"Keil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"Reichelt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,12,16]]},"reference":[{"key":"nr2064_bb1","unstructured":"Brandenburg, K. 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