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The dithiocarbamate ligands are chelating, forming similar Cd\u2014S bond lengths and define the approximate basal plane. One of the N atoms of the piperazine molecule, which adopts a chair conformation, occupies the apical site. In the crystal, supramolecular layers propagating in the<jats:italic>ac<\/jats:italic>plane are formed<jats:italic>via<\/jats:italic>hydroxy-O\u2014H...O(hydroxy), hydroxy-O\u2014H...N(terminal-piperazine) and coordinated-piperazine-N\u2014H...O(hydroxy) hydrogen bonds; the layers also feature methine-C\u2014H...S interactions and S...S [3.3714\u2005(10)\u2005\u00c5] short contacts. The layers stack along the<jats:italic>b-<\/jats:italic>axis direction with very weak terminal-piperazine-N\u2014H...O(hydroxy) interactions between them. 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