{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T08:57:14Z","timestamp":1758272234372,"version":"3.33.0"},"reference-count":30,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2016,1,23]],"date-time":"2016-01-23T00:00:00Z","timestamp":1453507200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,1,23]],"date-time":"2016-01-23T00:00:00Z","timestamp":1453507200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,2,1]]},"abstract":"<jats:p>The molecular structure of the tetrakis(triphenylphosphanyl)disilver salt of butane-1,1,4,4-tetracarboxylic acid, [Ag<jats:sub>2<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>8<\/jats:sub>)(C<jats:sub>18<\/jats:sub>H<jats:sub>15<\/jats:sub>P)<jats:sub>4<\/jats:sub>]\u00b73CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, crystallizes with one and a half molecules of dichloromethane in the asymmetric unit. The coordination complex exhibits an inversion centre through the central CH<jats:sub>2<\/jats:sub>\u2014CH<jats:sub>2<\/jats:sub>bond. The Ag<jats:sup>I<\/jats:sup>atom has a distorted trigonal\u2013planar P<jats:sub>2<\/jats:sub>O coordination environment. The packing is characterized by intermolecular<jats:italic>T<\/jats:italic>-shaped \u03c0\u2013\u03c0 interactions between the phenyl rings of the PPh<jats:sub>3<\/jats:sub>substituents in neighbouring molecules, forming a ladder-type superstructure parallel to [010]. These ladders are arranged in layers parallel to (101). Intramolecular hydrogen bonds between the OH group and one O atom of the Ag-bonded carboxylate group results in an asymmetric bidendate coordination of the carboxylate moiety to the Ag<jats:sup>I<\/jats:sup>ion.<\/jats:p>","DOI":"10.1107\/s2056989016000797","type":"journal-article","created":{"date-parts":[[2016,1,21]],"date-time":"2016-01-21T16:07:16Z","timestamp":1453392436000},"page":"215-219","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of (\u03bc-1,4-dicarboxybutane-1,4-dicarboxylato)bis[bis(triphenylphosphane)silver(I)] dichloromethane trisolvate"],"prefix":"10.1107","volume":"72","author":[{"given":"Peter","family":"Frenzel","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marcus","family":"Korb","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Heinrich","family":"Lang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,1,23]]},"reference":[{"key":"zl2653_bb1","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1002\/1521-3862(200105)7:3<117::AID-CVDE117>3.0.CO;2-7","volume":"7","author":"Chi","year":"2001","journal-title":"Chem. 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