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The Cd<jats:sup>II<\/jats:sup>cations are octahedrally coordinated by the pyridine N atom of two pyridine-4-carbothioamide ligands and by the S and N atoms of four thiocyanate anions and are linked into chains along [010] by pairs of anionic ligands. These chains are further linked into layers extending along (201) by intermolecular N\u2014H...O and O\u2014H...S hydrogen bonds. One of the amino H atoms of the pyridine-4-carbothioamide ligand is hydrogen-bonded to the O atom of a methanol molecule, and a symmetry-related methanol molecule is the donor group to the S atom of another pyridine-4-carbothioamide ligand whereby each of the pyridine-4-carbothioamide ligands forms two pairs of centrosymmetric N\u2014H...S and O\u2014H...S hydrogen bonds. The methanol molecules are equally disordered over two orientations.<\/jats:p>","DOI":"10.1107\/s2056989016002632","type":"journal-article","created":{"date-parts":[[2016,2,19]],"date-time":"2016-02-19T09:32:40Z","timestamp":1455874360000},"page":"370-373","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of<i>catena<\/i>-poly[[[bis(pyridine-4-carbothioamide-\u03ba<i>N<\/i><sup>1<\/sup>)cadmium]-di-\u03bc-thiocyanato-\u03ba<sup>2<\/sup><i>N<\/i>:<i>S<\/i>;\u03ba<sup>2<\/sup><i>S<\/i>:<i>N<\/i>] methanol disolvate]"],"prefix":"10.1107","volume":"72","author":[{"given":"Tristan","family":"Neumann","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,2,20]]},"reference":[{"key":"wm5271_bb1","doi-asserted-by":"crossref","first-page":"587","DOI":"10.1016\/j.poly.2011.10.013","volume":"31","author":"Boeckmann","year":"2012","journal-title":"Polyhedron"},{"key":"wm5271_bb2","unstructured":"Brandenburg, K. 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