{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:49Z","timestamp":1736831809644,"version":"3.33.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2016,3,31]],"date-time":"2016-03-31T00:00:00Z","timestamp":1459382400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,3,31]],"date-time":"2016-03-31T00:00:00Z","timestamp":1459382400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,4,1]]},"abstract":"<jats:p>The cation of the title solvated salt, C<jats:sub>42<\/jats:sub>H<jats:sub>42<\/jats:sub>N<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub><jats:sup>2+<\/jats:sup>\u00b72Br<jats:sup>\u2212<\/jats:sup>\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, lies on a crystallographic twofold rotation axis. The 1,2-diaminocyclohexane fragment has a chair conformation with two N atoms in a<jats:italic>transoid<\/jats:italic>conformation [N\u2014C\u2014C\u2014N = 163.4\u2005(2)\u00b0]. In the crystal, the cations are linked to the anions by N\u2014H...Br and C\u2014H...Br hydrogen bonds, forming a chain structure along the<jats:italic>c<\/jats:italic>axis. The dichloromethane molecule takes part in the hydrogen-bond network through C\u2014H...\u03c0 and C\u2014H...Br interactions.<\/jats:p>","DOI":"10.1107\/s2056989016004576","type":"journal-article","created":{"date-parts":[[2016,3,31]],"date-time":"2016-03-31T09:57:53Z","timestamp":1459418273000},"page":"559-562","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of (\u00b1)-[<i>trans<\/i>-cyclohexane-1,2-diylbis(azanediyl)]diphosphonium dibromide dichloromethane disolvate"],"prefix":"10.1107","volume":"72","author":[{"given":"Aurora","family":"Rodr\u00edguez \u00c1lvarez","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hugo","family":"Tlahuext","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jean-Michel","family":"Gr\u00e9vy","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,3,31]]},"reference":[{"key":"is5441_bb1","unstructured":"Agilent (2014). 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