{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T18:39:29Z","timestamp":1774550369838,"version":"3.50.1"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2016,5,20]],"date-time":"2016-05-20T00:00:00Z","timestamp":1463702400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,5,20]],"date-time":"2016-05-20T00:00:00Z","timestamp":1463702400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,6,1]]},"abstract":"<jats:p>The title compound, nonasodium chromium(III) hexakis[molybdate(VI)], \u03b2-Na<jats:sub>9<\/jats:sub>CrMo<jats:sub>6<\/jats:sub>O<jats:sub>24<\/jats:sub>, was prepared by solid-state reactions. This alluaudite-type structure is constituted of infinite layers formed by links between<jats:italic>M<\/jats:italic><jats:sub>2<\/jats:sub>O<jats:sub>10<\/jats:sub>(<jats:italic>M<\/jats:italic>= C\/Na) dimers and MoO<jats:sub>4<\/jats:sub>tetrahedra. The Na<jats:sup>+<\/jats:sup>and Cr<jats:sup>3+<\/jats:sup>cations are located in the same site with, respectively, 0.25 and 0.75 occupancies. The layers are connected to each other through MoO<jats:sub>4<\/jats:sub>sharing corners, resulting an in open three-dimensional framework with hexagonal-form cavities occupied by Na<jats:sup>+<\/jats:sup>cations. The proposed structural model is supported by charge-distribution (CHARDI) and bond-valence-sum (BVS) analysis. All atoms are on general positions except for one Mo, two Na (site symmetry 2) and another Na site (site symmetry -1). A comparison is made with the similar structures Na<jats:sub>4<\/jats:sub>Co(MoO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>, Na<jats:sub>2<\/jats:sub>Ni(MoO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>, Cu<jats:sub>1.35<\/jats:sub>Fe<jats:sub>3<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>and NaAgFeMn<jats:sub>2<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>.<\/jats:p>","DOI":"10.1107\/s205698901600774x","type":"journal-article","created":{"date-parts":[[2016,5,20]],"date-time":"2016-05-20T16:01:01Z","timestamp":1463760061000},"page":"833-837","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":8,"title":["Elaboration, \u00e9tude structurale et analyse CHARDI et BVS d'une nouvelle vari\u00e9t\u00e9 \u03b2-Na<sub>9<\/sub>Cr(MoO<sub>4<\/sub>)<sub>6<\/sub>de type alluaudite"],"prefix":"10.1107","volume":"72","author":[{"given":"Manel","family":"Sonni","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Riadh","family":"Marzouki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohamed Faouzi","family":"Zid","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Amira","family":"Souilem","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,5,20]]},"reference":[{"key":"ru2067_bb1","unstructured":""},{"key":"ru2067_bb2","first-page":"634","volume":"55","author":"Bazarov","year":"2010","journal-title":"Kristallografiya"},{"key":"ru2067_bb3","unstructured":"Brandenburg, K. & Putz, H. 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