{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:15Z","timestamp":1740174555991,"version":"3.37.3"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2016,6,10]],"date-time":"2016-06-10T00:00:00Z","timestamp":1465516800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,6,10]],"date-time":"2016-06-10T00:00:00Z","timestamp":1465516800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,7,1]]},"abstract":"<jats:p>In the title complexes,<jats:italic>trans<\/jats:italic>-dichlorido(4-chloroaniline-\u03ba<jats:italic>N<\/jats:italic>){3-methoxy-4-methoxycarbonylmethoxy-1-[(2,3-\u03b7)-prop-2-en-1-yl]benzene}platinum(II) 0.1-hydrate, [PtCl<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>ClN)(C<jats:sub>13<\/jats:sub>H<jats:sub>16<\/jats:sub>O<jats:sub>4<\/jats:sub>)]\u00b70.1H<jats:sub>2<\/jats:sub>O, (I), and<jats:italic>trans<\/jats:italic>-dichlorido(4-chloroaniline-\u03ba<jats:italic>N<\/jats:italic>){4-ethoxycarbonylmethoxy-3-methoxy-1-[(2,3-\u03b7)-prop-2-en-1-yl]benzene}platinum(II), [PtCl<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>ClN)(C<jats:sub>14<\/jats:sub>H<jats:sub>18<\/jats:sub>O<jats:sub>4<\/jats:sub>)], (II), the Pt<jats:sup>II<\/jats:sup>metal atom displays a slightly distorted square-planar coordination geometry defined by the aniline N atom, two chloride anions (<jats:italic>trans<\/jats:italic>-positioned) and one ethylenic double bond. The least-squares planes through the two aromatic ring systems make an angle of 47.3\u2005(3)\u00b0 for (I) and 38.6\u2005(2)\u00b0 for (II). Both structures show disorder for the PtCl<jats:sub>2<\/jats:sub>fragment, in the case of (I) even further extended towards the CH<jats:sub>2<\/jats:sub>\u2014CH=CH<jats:sub>2<\/jats:sub>ligand. An intramolecular C\u2014H...Cl hydrogen bond occurs in (I). In the crystal packing of (I), which is dominated by N\u2014H...O and C\u2014H...Cl interactions, a partially occupied water molecule is observed on a twofold rotation axis with a refined site occupancy of 0.10\u2005(1). A C\u2014H...\u03c0 interaction is also present. In (II), inversion dimers form chains along the<jats:italic>b-<\/jats:italic>axis direction by N\u2014H...O hydrogen bonds.<\/jats:p>","DOI":"10.1107\/s2056989016008872","type":"journal-article","created":{"date-parts":[[2016,6,10]],"date-time":"2016-06-10T08:45:06Z","timestamp":1465548306000},"page":"912-917","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structures of organoplatinum complexes containing alkyleugenoxyacetate and<i>p<\/i>-chloroaniline"],"prefix":"10.1107","volume":"72","author":[{"given":"Hai","family":"Le Thi Hong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Diep","family":"Dao Thi Bich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ngan","family":"Nguyen Bich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2186-5209","authenticated-orcid":true,"given":"Luc","family":"Van Meervelt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,6,10]]},"reference":[{"key":"rz5189_bb1","unstructured":"Agilent (2012). 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