{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:48Z","timestamp":1736831868205,"version":"3.33.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2016,8,12]],"date-time":"2016-08-12T00:00:00Z","timestamp":1470960000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,8,12]],"date-time":"2016-08-12T00:00:00Z","timestamp":1470960000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2016,8,8]]},"published-print":{"date-parts":[[2016,9,1]]},"abstract":"<jats:p>The structure of the title compound, [CrCl<jats:sub>2<\/jats:sub>(tn)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>[Cr<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>] (tn = propane-1,3-diamine; C<jats:sub>3<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>2<\/jats:sub>), has been determined from synchrotron data. The asymmetric unit contains one Cr<jats:sup>III<\/jats:sup> complex cation and half a [Cr<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion. In the complex cation, the Cr<jats:sup>III<\/jats:sup> ion is coordinated by the four N atoms of two propane-1,3-diamine (tn) ligands in the equatorial plane and by two Cl atoms in a <jats:italic>trans<\/jats:italic> configuration, displaying a distorted octahedral coordination sphere. The two six-membered rings in the complex cation have an <jats:italic>anti<\/jats:italic> chair\u2013chair conformation with respect to each other. The mean Cr\u2014N(tn) and Cr\u2014Cl bond lengths are 2.09\u2005(1) and 2.320\u2005(2)\u2005\u00c5, respectively. The slightly bent dichromate anion is disordered over two sets of sites (occupancy ratio = 0.7:0.3) and has a staggered conformation. The crystal structure is stabilized by intermolecular hydrogen bonds involving the NH<jats:sub>2<\/jats:sub> groups of the tn ligands as donors and the O atoms of the [Cr<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion and chlorido ligands as acceptors.<\/jats:p>","DOI":"10.1107\/s2056989016012755","type":"journal-article","created":{"date-parts":[[2016,8,12]],"date-time":"2016-08-12T07:25:02Z","timestamp":1470986702000},"page":"1293-1296","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of bis[<i>trans<\/i>-dichloridobis(propane-1,3-diamine-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)chromium(III)] dichromate from synchrotron data"],"prefix":"10.1107","volume":"72","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Keon Sang","family":"Ryoo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5109-771X","authenticated-orcid":true,"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,8,12]]},"reference":[{"key":"wm5308_bb1","doi-asserted-by":"crossref","first-page":"933","DOI":"10.1139\/v68-155","volume":"46","author":"Brandon","year":"1968","journal-title":"Can. J. Chem."},{"key":"wm5308_bb2","doi-asserted-by":"crossref","first-page":"m381","DOI":"10.1107\/S1600536811006349","volume":"67","author":"Choi","year":"2011","journal-title":"Acta Cryst. E"},{"key":"wm5308_bb3","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1002\/zaac.201100372","volume":"638","author":"Choi","year":"2012","journal-title":"Z. Anorg. Allg. Chem."},{"key":"wm5308_bb4","doi-asserted-by":"crossref","first-page":"1681","DOI":"10.1039\/C2CS35290G","volume":"42","author":"Fabbrizzi","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"wm5308_bb5","doi-asserted-by":"crossref","first-page":"2279","DOI":"10.1021\/ic00037a051","volume":"31","author":"Gadre","year":"1992","journal-title":"Inorg. Chem."},{"key":"wm5308_bb6","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/S1093-0191(02)00004-7","volume":"7","author":"Goyal","year":"2003","journal-title":"Adv. Environ. Res."},{"key":"wm5308_bb7","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"wm5308_bb8","doi-asserted-by":"crossref","first-page":"741","DOI":"10.1016\/0020-1650(70)80090-3","volume":"6","author":"House","year":"1970","journal-title":"Inorg. Nucl. Chem. Lett."},{"key":"wm5308_bb9","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1023\/A:1011080110767","volume":"26","author":"Kou","year":"2001","journal-title":"Transition Met. Chem."},{"key":"wm5308_bb10","doi-asserted-by":"crossref","first-page":"m832","DOI":"10.1107\/S1600536812023355","volume":"68","author":"Moon","year":"2012","journal-title":"Acta Cryst. E"},{"key":"wm5308_bb11","doi-asserted-by":"crossref","first-page":"1336","DOI":"10.1107\/S2056989015019258","volume":"71","author":"Moon","year":"2015","journal-title":"Acta Cryst. E"},{"key":"wm5308_bb12","unstructured":"Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter Jr & R. M. Sweet, pp. 307-326. New York: Academic Press."},{"key":"wm5308_bb13","unstructured":"Putz, H. & Brandenburg, K. (2014). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"wm5308_bb14","doi-asserted-by":"crossref","first-page":"3489","DOI":"10.1039\/c3cs35429f","volume":"42","author":"Santos-Figueroa","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"wm5308_bb15","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm5308_bb16","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm5308_bb17","doi-asserted-by":"crossref","first-page":"369","DOI":"10.1107\/S1600577515021633","volume":"23","author":"Shin","year":"2016","journal-title":"J. Synchrotron Rad."},{"key":"wm5308_bb18","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1007\/BF01160488","volume":"15","author":"Vaughn","year":"1985","journal-title":"J. Crystallogr. Spectrosc. Res."},{"key":"wm5308_bb19","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"wm5308_bb20","doi-asserted-by":"crossref","first-page":"1019","DOI":"10.1016\/j.jhazmat.2008.05.134","volume":"162","author":"Yusof","year":"2009","journal-title":"J. Hazard. Mater."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2016\/09\/00\/wm5308\/wm5308.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2016\/09\/00\/wm5308\/wm5308.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:50:24Z","timestamp":1736765424000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989016012755"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,8,12]]},"references-count":20,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2016,9]]}},"alternative-id":["S2056989016012755"],"URL":"https:\/\/doi.org\/10.1107\/s2056989016012755","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989016012755\/wm5308sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989016012755\/wm5308Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2016,8,12]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5308","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"8 July 2016","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"8 August 2016","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 August 2016","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5308"}},{"value":"\u00a9 2016 Moon et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}