{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:18:28Z","timestamp":1736831908995,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T00:00:00Z","timestamp":1473379200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T00:00:00Z","timestamp":1473379200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2016,8,27]]},"published-print":{"date-parts":[[2016,10,1]]},"abstract":"<jats:p>In the polymeric title compound, [CdCl<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, the central Cd<jats:sup>II<\/jats:sup> atom is coordinated by four chloride ligands and two N atoms from a chelating 2,2\u2032-bi-1<jats:italic>H<\/jats:italic>-imidazole molecule, leading to a distorted octahedral Cl<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub> coordination set. As a result of the \u03bc<jats:sub>2<\/jats:sub>-bridging character of the Cl ligands, chains parallel to the <jats:italic>c<\/jats:italic> axis are formed, with the chelating 2,2\u2032-bi-1<jats:italic>H<\/jats:italic>-imidazole ligands decorated on both sides of the chain. The luminescence properties of the complex dispersed in dimethylformamide shows that the emission intensities are significantly quenched by nitrobenzene.<\/jats:p>","DOI":"10.1107\/s2056989016013736","type":"journal-article","created":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T07:34:16Z","timestamp":1473406456000},"page":"1421-1424","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and fluorescence properties of <i>catena<\/i>-poly[[(2,2\u2032-bi-1<i>H<\/i>-imidazole-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)cadmium]-di-\u03bc-chlorido]"],"prefix":"10.1107","volume":"72","author":[{"given":"Yang","family":"Liu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hai-Hui","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,9,9]]},"reference":[{"key":"wm5319_bb1","doi-asserted-by":"crossref","first-page":"846","DOI":"10.1039\/b718790d","volume":"10","author":"Brown","year":"2008","journal-title":"CrystEngComm"},{"key":"wm5319_bb2","unstructured":"Bruker (2012). 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