{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:53Z","timestamp":1736831873857,"version":"3.33.0"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T00:00:00Z","timestamp":1473379200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T00:00:00Z","timestamp":1473379200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2016,9,5]]},"published-print":{"date-parts":[[2016,10,1]]},"abstract":"<jats:p>In the asymmetric unit of the title compound, [CrCl<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)][Cr(C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> (C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub> = 1,4,8,11-tetraazacyclotetradecane, cyclam; C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> = oxalate, ox), there are two independent halves of the [CrCl<jats:sub>2<\/jats:sub>(cyclam)]<jats:sup>+<\/jats:sup> and [Cr(ox)(cyclam)]<jats:sup>+<\/jats:sup> cations, and one perchlorate anion. In the complex cations, which are completed by application of twofold rotation symmetry, the Cr<jats:sup>III<\/jats:sup> ions are coordinated by the four N atoms of a cyclam ligand, and by two chloride ions or one oxalate bidentate ligand in a <jats:italic>cis<\/jats:italic> arrangement, displaying an overall distorted octahedral coordination environment. The Cr\u2014N(cyclam) bond lengths are in the range of 2.075\u2005(5) to 2.096\u2005(4)\u2005\u00c5 while the Cr\u2014Cl and Cr\u2014O(ox) bond lengths are 2.3358\u2005(14) and 1.956\u2005(4)\u2005\u00c5, respectively. Both cyclam moieties adopt the <jats:italic>cis<\/jats:italic>-V conformation. The slightly distorted tetrahedral ClO<jats:sub>4<\/jats:sub>\n                  <jats:sup>\u2212<\/jats:sup> anion remains outside the coordination sphere. The supramolecular architecture includes N\u2014H...O and N\u2014H...Cl hydrogen bonding between cyclam NH donor groups, O atoms of the oxalate ligand or ClO<jats:sub>4<\/jats:sub>\n                  <jats:sup>\u2212<\/jats:sup> anions and one Cl ligand as acceptors, leading to a three-dimensional network structure.<\/jats:p>","DOI":"10.1107\/s2056989016014134","type":"journal-article","created":{"date-parts":[[2016,9,9]],"date-time":"2016-09-09T07:34:16Z","timestamp":1473406456000},"page":"1417-1420","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Crystal structure of <i>cis<\/i>-dichlorido(1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>)chromium(III) (oxalato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>\n                  <sup>1<\/sup>,<i>O<\/i>\n                  <sup>2<\/sup>)(1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>)chromium(III) bis(perchlorate) from synchrotron data"],"prefix":"10.1107","volume":"72","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,9,9]]},"reference":[{"key":"wm5323_bb1","doi-asserted-by":"crossref","first-page":"4231","DOI":"10.1016\/j.ica.2009.05.024","volume":"362","author":"Choi","year":"2009","journal-title":"Inorg. 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