{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:18:41Z","timestamp":1736831921253,"version":"3.33.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2016,10,4]],"date-time":"2016-10-04T00:00:00Z","timestamp":1475539200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,10,4]],"date-time":"2016-10-04T00:00:00Z","timestamp":1475539200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2016,9,29]]},"published-print":{"date-parts":[[2016,11,1]]},"abstract":"<jats:p>The asymmetric unit of the title compound, {[Hg<jats:italic>L<\/jats:italic>Cl<jats:sub>2<\/jats:sub>]\u00b70.5CHCl<jats:sub>3<\/jats:sub>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:italic>L<\/jats:italic> = <jats:italic>N<\/jats:italic>-(pyridin-4-ylmethyl)pyridin-3-amine, C<jats:sub>11<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>3<\/jats:sub>), contains one Hg<jats:sup>II<\/jats:sup> ion, one bridging <jats:italic>L<\/jats:italic> ligand, two chloride ligands and a chloroform solvent molecule with half-occupancy that is disordered about a crystallographic twofold rotation axis. Each Hg<jats:sup>II<\/jats:sup> ion is coordinated by two pyridine N atoms from two symmetry-related <jats:italic>L<\/jats:italic> ligands and two chloride anions in a highly distorted tetrahedral geometry with bond angles falling in the range 99.05\u2005(17)\u2013142.96\u2005(7)\u00b0. Each <jats:italic>L<\/jats:italic> ligand bridges two Hg<jats:sup>II<\/jats:sup> ions, forming polymeric zigzag chains propagating in [010]. In the crystal, the chains are linked by intermolecular N\/C\u2014H...Cl hydrogen bonds together with weak C\u2014H...\u03c0 interactions, resulting in the formation of a three-dimensional supramolecular network, which is further stabilized by C\u2014Cl...\u03c0 interactions between the solvent chloroform molecules and the pyridine rings of <jats:italic>L<\/jats:italic> [chloride-to-centroid distances = 3.442\u2005(11) and 3.626\u2005(13)\u2005\u00c5]. In addition, weak Cl...Cl contacts [3.320\u2005(5)\u2005\u00c5] between the chloroform solvent molecules and the coordinating chloride anions are also observed.<\/jats:p>","DOI":"10.1107\/s2056989016015310","type":"journal-article","created":{"date-parts":[[2016,10,4]],"date-time":"2016-10-04T08:22:12Z","timestamp":1475569332000},"page":"1513-1516","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Crystal structure of an Hg<sup>II<\/sup> coordination polymer with an unsymmetrical dipyridyl ligand: <i>catena<\/i>-poly[[[dichloridomercury(II)]-\u03bc-<i>N<\/i>-(pyridin-4-ylmethyl)pyridin-3-amine-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>:<i>N<\/i>\u2032] chloroform hemisolvate]"],"prefix":"10.1107","volume":"72","author":[{"given":"Suk-Hee","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Donghyun","family":"Kang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ki-Min","family":"Park","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,10,4]]},"reference":[{"key":"sj5509_bb1","unstructured":"Brandenburg, K. (2010). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"sj5509_bb2","unstructured":"Bruker (2014). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"sj5509_bb3","doi-asserted-by":"crossref","first-page":"894","DOI":"10.1021\/ar300251k","volume":"46","author":"Chifotides","year":"2013","journal-title":"Acc. Chem. Res."},{"key":"sj5509_bb4","doi-asserted-by":"crossref","first-page":"5700","DOI":"10.1039\/C4CS00106K","volume":"43","author":"Furukawa","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"sj5509_bb5","doi-asserted-by":"crossref","first-page":"3658","DOI":"10.5012\/bkcs.2014.35.12.3658","volume":"35","author":"Ju","year":"2014","journal-title":"Bull. Korean Chem. Soc."},{"key":"sj5509_bb6","doi-asserted-by":"crossref","first-page":"6753","DOI":"10.1021\/ja029048y","volume":"125","author":"Khlobystov","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"sj5509_bb7","doi-asserted-by":"crossref","first-page":"1532","DOI":"10.1002\/bkcs.10274","volume":"36","author":"Lee","year":"2015","journal-title":"Bull. Korean Chem. Soc."},{"key":"sj5509_bb8","doi-asserted-by":"crossref","first-page":"3477","DOI":"10.5012\/bkcs.2013.34.11.3477","volume":"34","author":"Lee","year":"2013","journal-title":"Bull. Korean Chem. Soc."},{"key":"sj5509_bb9","doi-asserted-by":"crossref","first-page":"688","DOI":"10.1021\/cr100160e","volume":"111","author":"Leong","year":"2011","journal-title":"Chem. Rev."},{"key":"sj5509_bb10","doi-asserted-by":"crossref","first-page":"2911","DOI":"10.1002\/anie.200806219","volume":"48","author":"Matter","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"key":"sj5509_bb11","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1107\/S1600536814022922","volume":"70","author":"Moon","year":"2014","journal-title":"Acta Cryst. E"},{"key":"sj5509_bb12","doi-asserted-by":"crossref","first-page":"1287","DOI":"10.1107\/S205698901501837X","volume":"71","author":"Moon","year":"2015","journal-title":"Acta Cryst. E"},{"key":"sj5509_bb13","doi-asserted-by":"crossref","first-page":"m233","DOI":"10.1107\/S1600536814011465","volume":"70","author":"Moon","year":"2014","journal-title":"Acta Cryst. E"},{"key":"sj5509_bb14","doi-asserted-by":"crossref","first-page":"5113","DOI":"10.1039\/b805617j","author":"Robson","year":"2008","journal-title":"Dalton Trans."},{"key":"sj5509_bb15","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"sj5509_bb16","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"sj5509_bb17","doi-asserted-by":"crossref","first-page":"6774","DOI":"10.1039\/C5CS00307E","volume":"44","author":"Silva","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"sj5509_bb18","doi-asserted-by":"crossref","first-page":"9565","DOI":"10.1002\/chem.200800806","volume":"14","author":"Uemura","year":"2008","journal-title":"Chem. Eur. J."},{"key":"sj5509_bb19","doi-asserted-by":"crossref","first-page":"5914","DOI":"10.1021\/ic400055t","volume":"52","author":"Zhang","year":"2013","journal-title":"Inorg. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2016\/11\/00\/sj5509\/sj5509.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2016\/11\/00\/sj5509\/sj5509.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:54:28Z","timestamp":1736765668000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989016015310"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,10,4]]},"references-count":19,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2016,11]]}},"alternative-id":["S2056989016015310"],"URL":"https:\/\/doi.org\/10.1107\/s2056989016015310","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989016015310\/sj5509sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989016015310\/sj5509Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2016,10,4]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?sj5509","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"28 September 2016","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"29 September 2016","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 October 2016","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?sj5509"}},{"value":"\u00a9 2016 Moon et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}