{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T12:22:07Z","timestamp":1761394927282,"version":"3.33.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2017,1,1]],"date-time":"2017-01-01T00:00:00Z","timestamp":1483228800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,1,1]],"date-time":"2017-01-01T00:00:00Z","timestamp":1483228800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,1,1]]},"abstract":"<jats:p>Condensation of 8-hydroxyquinoline-2-carbaldehyde with 2-aminophenol gave the (<jats:italic>E<\/jats:italic>)-2-[(2-hydroxyphenylimino)methyl]quinolin-8-ol derivative that reacted with di-<jats:italic>n<\/jats:italic>-butyltin oxide with release of H<jats:sub>2<\/jats:sub>O to yield the chelate title complex, [Sn<jats:sub>2<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>16<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]. The compound crystallizes in the triclinic space group<jats:italic>P<\/jats:italic>-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetradentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted pentagonal\u2013bipyramidal SnC<jats:sub>2<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>coordination arising from the<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>\u2032-tetradentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites.<\/jats:p>","DOI":"10.1107\/s2056989016018867","type":"journal-article","created":{"date-parts":[[2016,12,1]],"date-time":"2016-12-01T17:07:20Z","timestamp":1480612040000},"page":"4-7","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of bis{\u03bc-(<i>E<\/i>)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-\u03ba<sup>4<\/sup><i>O<\/i>,<i>N<\/i>,<i>N<\/i>\u2032,<i>O<\/i>\u2032}bis[dibutyltin(IV)]"],"prefix":"10.1107","volume":"73","author":[{"given":"Camacho-Camacho","family":"Carlos","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ortiz-Pastrana","family":"Naytz\u00e9","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Garza-Ortiz","family":"Ariadna","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rojas-Oviedo","family":"Irma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,1,1]]},"reference":[{"key":"bg2598_bb1","doi-asserted-by":"crossref","first-page":"102","DOI":"10.3923\/ijcr.2006.102.108","volume":"2","author":"Rasoul-Amini","year":"2006","journal-title":"Int. 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