{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,5]],"date-time":"2026-04-05T14:21:25Z","timestamp":1775398885171,"version":"3.50.1"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2017,1,1]],"date-time":"2017-01-01T00:00:00Z","timestamp":1483228800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,1,1]],"date-time":"2017-01-01T00:00:00Z","timestamp":1483228800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,1,1]]},"abstract":"<jats:p>In the title compound, [Cd(C<jats:sub>13<\/jats:sub>H<jats:sub>11<\/jats:sub>IN<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>3<\/jats:sub>OH, which crystallizes with<jats:italic>Z<\/jats:italic>= 4 in the space group<jats:italic>Pbcn<\/jats:italic>, the Cd<jats:sup>II<\/jats:sup>atom is located on a twofold rotation axis and coordinated by two I<jats:sup>\u2212<\/jats:sup>anions and two N atoms from the pyridine rings of the two<jats:italic>N<\/jats:italic>\u2032-[(<jats:italic>E<\/jats:italic>)-4-hydroxybenzylidene]pyridine-4-carbohydrazide ligands. The geometry around the Cd<jats:sup>II<\/jats:sup>atom is distorted tetrahedral, with bond angles in the range 94.92\u2005(11)\u2013124.29\u2005(2)\u00b0. The iodide anions undergo intermolecular hydrogen-bonding contacts with the C\u2014H groups of the organic ligands of an adjacent complex molecule, generating a chain structure along the<jats:italic>b<\/jats:italic>axis. Furthermore, an extensive series of O\u2014H...O, N\u2014H...O and C\u2014H...O hydrogen-bonding interactions involving both the complex molecules and the ethanol solvate molecules generate a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989016019575","type":"journal-article","created":{"date-parts":[[2016,12,9]],"date-time":"2016-12-09T09:34:39Z","timestamp":1481276079000},"page":"28-30","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of bis{<i>N<\/i>\u2032-[(<i>E<\/i>)-4-hydroxybenzylidene]pyridine-4-carbohydrazide-\u03ba<i>N<\/i><sup>1<\/sup>}diiodidocadmium methanol disolvate"],"prefix":"10.1107","volume":"73","author":[{"given":"Farhad Akbari","family":"Afkhami","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Harald","family":"Krautscheid","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zeliha","family":"Atio\u011flu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mehmet","family":"Akkurt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,1,1]]},"reference":[{"key":"sj5516_bb1","doi-asserted-by":"crossref","first-page":"4587","DOI":"10.1039\/C6CE00877A","volume":"18","author":"Afkhami","year":"2016","journal-title":"CrystEngComm"},{"key":"sj5516_bb2","doi-asserted-by":"crossref","first-page":"m213","DOI":"10.1107\/S1600536814010630","volume":"70","author":"Akkurt","year":"2014","journal-title":"Acta Cryst. 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