{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,13]],"date-time":"2026-01-13T08:32:51Z","timestamp":1768293171522,"version":"3.49.0"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2017,1,27]],"date-time":"2017-01-27T00:00:00Z","timestamp":1485475200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,1,27]],"date-time":"2017-01-27T00:00:00Z","timestamp":1485475200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,2,1]]},"abstract":"<jats:p>The complete molecule of the title compound, [Sn(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>10<\/jats:sub>NOS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>], is generated by a crystallographic mirror plane, with the Sn<jats:sup>IV<\/jats:sup>atom and the two inner methylene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The dithiocarbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C<jats:sub>2<\/jats:sub>S<jats:sub>4<\/jats:sub>donor set defining a skew trapezoidal bipyramidal geometry; the<jats:italic>n<\/jats:italic>-butyl groups are disposed to lie over the longer Sn\u2014S bonds. Supramolecular chains aligned along the<jats:italic>a<\/jats:italic>-axis direction and sustained by methylene-C\u2014H...S(weakly coordinating) interactions feature in the molecular packing. A Hirshfeld surface analysis reveals the dominance of H...H contacts in the crystal.<\/jats:p>","DOI":"10.1107\/s2056989017001098","type":"journal-article","created":{"date-parts":[[2017,1,27]],"date-time":"2017-01-27T11:35:24Z","timestamp":1485516924000},"page":"260-265","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":11,"title":["Di-<i>n<\/i>-butylbis[<i>N<\/i>-(2-methoxyethyl)-<i>N<\/i>-methyldithiocarbamato-\u03ba<sup>2<\/sup><i>S<\/i>,<i>S<\/i>\u2032]tin(IV): crystal structure and Hirshfeld surface analysis"],"prefix":"10.1107","volume":"73","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2237-4161","authenticated-orcid":true,"given":"Rapidah","family":"Mohamad","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3772-2088","authenticated-orcid":true,"given":"Normah","family":"Awang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nurul F.","family":"Kamaludin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mukesh M.","family":"Jotani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. 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