{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:05:31Z","timestamp":1760299531460,"version":"3.33.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2017,2,21]],"date-time":"2017-02-21T00:00:00Z","timestamp":1487635200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,2,21]],"date-time":"2017-02-21T00:00:00Z","timestamp":1487635200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,3,1]]},"abstract":"<jats:p>The asymmetric unit of the title compound, [Cd<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>4<\/jats:sub>NO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>], contains one Cd<jats:sup>II<\/jats:sup>atom, two 3-nitrobenzoate (NB) anions and two 3-cyanopyridine (CPy) ligands. The two CPy ligands act as monodentate N(pyridine)-bonding ligands, while the two NB anions act as bidentate ligands through the carboxylate O atoms. The centrosymmetric dinuclear complex is generated by application of inversion symmetry, whereby the Cd<jats:sup>II<\/jats:sup>atoms are bridged by the carboxylate O atoms of two symmetry-related NB anions, thus completing the distorted N<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>pentagonal\u2013bipyramidal coordination sphere of each Cd<jats:sup>II<\/jats:sup>atom. The benzene and pyridine rings are oriented at dihedral angles of 10.02\u2005(7) and 5.76\u2005(9)\u00b0, respectively. In the crystal, C\u2014H...N hydrogen bonds link the molecules, enclosing<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(26) ring motifs, in which they are further linked<jats:italic>via<\/jats:italic>C\u2014H...O hydrogen bonds, resulting in a three-dimensional network. In addition, \u03c0\u2013\u03c0 stacking interactions between parallel benzene rings and between parallel pyridine rings of adjacent molecules [shortest centroid-to-centroid distances = 3.885\u2005(1) and 3.712\u2005(1)\u2005\u00c5, respectively], as well as a weak C\u2014H...\u03c0 interaction, may further stabilize the crystal structure.<\/jats:p>","DOI":"10.1107\/s2056989017002675","type":"journal-article","created":{"date-parts":[[2017,2,21]],"date-time":"2017-02-21T10:05:44Z","timestamp":1487671544000},"page":"413-416","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of bis(\u03bc-3-nitrobenzoato)-\u03ba<sup>3<\/sup><i>O<\/i>,<i>O<\/i>\u2032:<i>O<\/i>;\u03ba<sup>3<\/sup><i>O<\/i>:<i>O<\/i>,<i>O<\/i>\u2032-bis[bis(3-cyanopyridine-\u03ba<i>N<\/i><sup>1<\/sup>)(3-nitrobenzoato-\u03ba<sup>2<\/sup><i>O<\/i>,<i>O<\/i>\u2032)cadmium]"],"prefix":"10.1107","volume":"73","author":[{"given":"Tuncer","family":"H\u00f6kelek","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nurcan","family":"Akduran","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Azer","family":"\u00d6zen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00fcvent\u00fcrk","family":"U\u011furlu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hacali","family":"Necefo\u011flu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,2,21]]},"reference":[{"key":"wm5366_bb1","doi-asserted-by":"crossref","first-page":"3079","DOI":"10.1107\/S0567740878010110","volume":"34","author":"Adiwidjaja","year":"1978","journal-title":"Acta Cryst. 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