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The resulting S<jats:sub>5<\/jats:sub>donor set defines a Cd<jats:sup>II<\/jats:sup>coordination geometry intermediate between square-pyramidal and trigonal\u2013bipyramidal, but tending towards the former. The packing features C\u2014H...S and C\u2014H...\u03c0 interactions, which generate a three-dimensional network. 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