{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,21]],"date-time":"2025-09-21T17:30:00Z","timestamp":1758475800749,"version":"3.37.3"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2017,3,10]],"date-time":"2017-03-10T00:00:00Z","timestamp":1489104000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,3,10]],"date-time":"2017-03-10T00:00:00Z","timestamp":1489104000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,4,1]]},"abstract":"<jats:p>The title compound, {[Cd(C<jats:sub>9<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7C<jats:sub>6<\/jats:sub>H<jats:sub>7<\/jats:sub>N}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, features two \u03bc<jats:sub>2<\/jats:sub>-\u03ba<jats:sup>3<\/jats:sup>-dithiocarbamate ligands each of which chelates one Cd<jats:sup>II<\/jats:sup>atom,<jats:italic>via<\/jats:italic>the S atoms, while simultaneously bridging to another<jats:italic>via<\/jats:italic>the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the<jats:italic>ab<\/jats:italic>plane with square channels along the<jats:italic>b<\/jats:italic>axis. The Cd<jats:sup>II<\/jats:sup>atom geometry is based on a distorted<jats:italic>cis<\/jats:italic>-N<jats:sub>2<\/jats:sub>S<jats:sub>4<\/jats:sub>octahedron. The 3-methylpyridine molecules reside in the channels aligned along the<jats:italic>b<\/jats:italic>axis, being held in place by methylene-C\u2014H...N(3-methylpyridine) and (3-methylpyridine)-C\u2014H...\u03c0(pyridyl) interactions. Pyridyl-C\u2014H...S and dithiocarbamate-methyl-C\u2014H...\u03c0(pyridyl) interactions provide connections between layers along the<jats:italic>c<\/jats:italic>axis.<\/jats:p>","DOI":"10.1107\/s2056989017003516","type":"journal-article","created":{"date-parts":[[2017,3,10]],"date-time":"2017-03-10T08:43:50Z","timestamp":1489135430000},"page":"488-492","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A two-dimensional coordination polymer: poly[[bis[\u03bc<sub>2<\/sub>-<i>N<\/i>-ethyl-<i>N<\/i>-(pyridin-4-ylmethyl)dithiocarbamato-\u03ba<sup>3<\/sup><i>N<\/i>:<i>S<\/i>,<i>S<\/i>\u2032]cadmium(II)] 3-methylpyridine monosolvate]"],"prefix":"10.1107","volume":"73","author":[{"given":"Hadi D.","family":"Arman","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pavel","family":"Poplaukhin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. T.","family":"Tiekink","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,3,10]]},"reference":[{"key":"hb7664_bb1","doi-asserted-by":"crossref","first-page":"m479","DOI":"10.1107\/S1600536813021569","volume":"69","author":"Arman","year":"2013","journal-title":"Acta Cryst. E"},{"key":"hb7664_bb2","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1107\/S2056989016012214","volume":"72","author":"Arman","year":"2016","journal-title":"Acta Cryst. E"},{"key":"hb7664_bb3","doi-asserted-by":"crossref","first-page":"m1425","DOI":"10.1107\/S1600536806018770","volume":"62","author":"Avila","year":"2006","journal-title":"Acta Cryst. E"},{"key":"hb7664_bb4","doi-asserted-by":"crossref","first-page":"422","DOI":"10.1002\/hc.21032","volume":"23","author":"Barba","year":"2012","journal-title":"Heteroat. Chem."},{"key":"hb7664_bb5","unstructured":"Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"hb7664_bb6","doi-asserted-by":"crossref","first-page":"m320","DOI":"10.1107\/S1600536811004508","volume":"67","author":"Broker","year":"2011","journal-title":"Acta Cryst. E"},{"key":"hb7664_bb7","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1002\/aoc.419","volume":"17","author":"Chai","year":"2003","journal-title":"Appl. Organomet. Chem."},{"key":"hb7664_bb8","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"hb7664_bb9","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/j.ica.2015.11.011","volume":"441","author":"Ferreira","year":"2016","journal-title":"Inorg. Chim. Acta"},{"key":"hb7664_bb10","unstructured":"Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan."},{"key":"hb7664_bb11","doi-asserted-by":"crossref","first-page":"1085","DOI":"10.1107\/S2056989016010768","volume":"72","author":"Jotani","year":"2016","journal-title":"Acta Cryst. E"},{"key":"hb7664_bb12","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1515\/zkri-2016-1943","volume":"231","author":"Jotani","year":"2016","journal-title":"Z. Kristallogr."},{"key":"hb7664_bb13","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.jorganchem.2016.08.007","volume":"820","author":"Kumar","year":"2016","journal-title":"J. Organomet. Chem."},{"key":"hb7664_bb14","doi-asserted-by":"crossref","first-page":"6765","DOI":"10.1039\/c4ce00510d","volume":"16","author":"Kumar","year":"2014","journal-title":"CrystEngComm"},{"key":"hb7664_bb15","unstructured":"Molecular Structure Corporation & Rigaku (2005). CrystalClear. MSC, The Woodlands, Texas, USA, and Rigaku Corporation, Tokyo, Japan."},{"key":"hb7664_bb16","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ica.2013.03.010","volume":"401","author":"Onwudiwe","year":"2013","journal-title":"Inorg. Chim. Acta"},{"key":"hb7664_bb17","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"hb7664_bb18","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/j.ica.2011.01.006","volume":"368","author":"Rodina","year":"2011","journal-title":"Inorg. Chim. Acta"},{"key":"hb7664_bb19","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"hb7664_bb20","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"hb7664_bb21","doi-asserted-by":"crossref","first-page":"3737","DOI":"10.1039\/C4NJ00435C","volume":"38","author":"Singh","year":"2014","journal-title":"New J. Chem."},{"key":"hb7664_bb22","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1515\/zkri-2015-1889","volume":"231","author":"Tan","year":"2016","journal-title":"Z. Kristallogr."},{"key":"hb7664_bb23","doi-asserted-by":"crossref","unstructured":"Tan, Y. S., Sudlow, A. L., Molloy, K. C., Morishima, Y., Fujisawa, K., Jackson, W. J., Henderson, W., Halim, S. N. Bt A., Ng, S. W. & Tiekink, E. R. T. (2013). Cryst. Growth Des. 13, 3046-3056.","DOI":"10.1021\/cg400453x"},{"key":"hb7664_bb24","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1039\/b301318a","volume":"5","author":"Tiekink","year":"2003","journal-title":"CrystEngComm"},{"key":"hb7664_bb25","doi-asserted-by":"crossref","first-page":"533","DOI":"10.1002\/aoc.1441","volume":"22","author":"Tiekink","year":"2008","journal-title":"Appl. Organomet. Chem."},{"key":"hb7664_bb26","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"hb7664_bb27","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1016\/j.ica.2014.05.031","volume":"421","author":"Yadav","year":"2014","journal-title":"Inorg. Chim. Acta"}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/04\/00\/hb7664\/hb7664.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/04\/00\/hb7664\/hb7664.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:11:17Z","timestamp":1736763077000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989017003516"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,3,10]]},"references-count":27,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2017,4]]}},"alternative-id":["S2056989017003516"],"URL":"https:\/\/doi.org\/10.1107\/s2056989017003516","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2017,3,10]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb7664","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"2 March 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 March 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"10 March 2017","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb7664"}},{"value":"\u00a9 2017 Armanet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}