{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:54Z","timestamp":1736844594433,"version":"3.33.0"},"reference-count":10,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2017,5,16]],"date-time":"2017-05-16T00:00:00Z","timestamp":1494892800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,5,16]],"date-time":"2017-05-16T00:00:00Z","timestamp":1494892800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2017,5,10]]},"published-print":{"date-parts":[[2017,6,1]]},"abstract":"<jats:p>Reaction of chromium(III) precursors with TeO<jats:sub>2<\/jats:sub> in PbF<jats:sub>2<\/jats:sub>\/PbO melts in air led to oxidation of chromium(III) to chromium(VI), whereas tellurium remained its oxidation state of IV. In the resulting title compound, Pb<jats:sub>2<\/jats:sub>(CrO<jats:sub>4<\/jats:sub>)(TeO<jats:sub>3<\/jats:sub>), the two types of anions are isolated from each other, hence a double salt is formed. The two independent Pb<jats:sup>2+<\/jats:sup> cations exhibit coordination number nine under formation of very distorted coordination polyhedra [bond-length range = 2.363\u2005(6)\u20133.276\u2005(7)\u2005\u00c5]. The oxochromate(VI) and oxotellurate(IV) anions have tetrahedral and trigonal\u2013pyramidal configurations, respectively. In the crystal structure, (001) layers of metal cations alternate with layers of TeO<jats:sub>3<\/jats:sub>\n                  <jats:sup>2\u2212<\/jats:sup> and CrO<jats:sub>4<\/jats:sub>\n                  <jats:sup>2\u2212<\/jats:sup> anions along [001], forming a three-dimensional framework structure. Pb<jats:sub>2<\/jats:sub>(CrO<jats:sub>4<\/jats:sub>)(TeO<jats:sub>3<\/jats:sub>) is isotypic with its sulfate analogue Pb<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(TeO<jats:sub>3<\/jats:sub>) and is comparatively discussed.<\/jats:p>","DOI":"10.1107\/s2056989017006995","type":"journal-article","created":{"date-parts":[[2017,5,16]],"date-time":"2017-05-16T08:34:56Z","timestamp":1494923696000},"page":"853-855","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of dilead(II) oxochromate(VI) oxotellurate(IV)"],"prefix":"10.1107","volume":"73","author":[{"given":"Matthias","family":"Weil","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,5,16]]},"reference":[{"key":"hb7677_bb1","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1107\/S0108768198010969","volume":"55","author":"Bergerhoff","year":"1999","journal-title":"Acta Cryst. 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