{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:25Z","timestamp":1740174565175,"version":"3.37.3"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2017,6,2]],"date-time":"2017-06-02T00:00:00Z","timestamp":1496361600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,6,2]],"date-time":"2017-06-02T00:00:00Z","timestamp":1496361600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/100007254","name":"Creighton University","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100007254","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Hamilton Company"},{"name":"Cambridge Isotope Laboratories, Inc."},{"DOI":"10.13039\/100000165","name":"National Science Foundation, Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-0349258"],"award-info":[{"award-number":["CHE-0349258"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,7,1]]},"abstract":"<jats:p>The first Fe<jats:sup>III<\/jats:sup>atom in the solvated title compound, [Fe<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>O(C<jats:sub>26<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>4<\/jats:sub>)]\u00b7CHCl<jats:sub>3<\/jats:sub>, adopts a distorted six-coordinate octahedral geometry. It is coordinated by one chloride ligand, four N atoms from the (1<jats:italic>R<\/jats:italic>,2<jats:italic>R<\/jats:italic>)-<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis[(quinolin-2-yl)methyl]cyclohexane-1,2-diamine ligand, and a bridging oxido ligand attached to the second Fe<jats:sup>III<\/jats:sup>atom, which is also bonded to three chloride ions. A very weak intramolecular N\u2014H...Cl hydrogen bond occurs. In the crystal, the coordination complexes stack in columns, and a grouping of six such columns create channels, which are populated by disordered chloroform solvent molecules. Although the Fe\u2014Cl bond lengths for the two metal atoms are comparable to the mean Fe\u2014Cl bond lengths as derived from the Cambridge Structural Database, the Fe\u2014O bond lengths are notably shorter. The solvent chloroform molecule exhibits `flip' disorder of the C\u2014H moiety in a 0.544\u2005(3):0.456\u2005(3) ratio. The only directional interaction noted is a weak C\u2014H...Cl hydrogen bond.<\/jats:p>","DOI":"10.1107\/s2056989017007952","type":"journal-article","created":{"date-parts":[[2017,6,2]],"date-time":"2017-06-02T09:06:09Z","timestamp":1496394369000},"page":"936-940","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of ({(1<i>R<\/i>,2<i>R<\/i>)-<i>N<\/i>,<i>N<\/i>\u2032-bis[(quinolin-2-yl)methyl]cyclohexane-1,2-diamine}chloridoiron(III))-\u03bc-oxido-[trichloridoferrate(III)] chloroform monosolvate"],"prefix":"10.1107","volume":"73","author":[{"given":"Hannah","family":"Swift","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Molly W.","family":"Carrig","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kayode D.","family":"Oshin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anastasiya I.","family":"Vinokur","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"John A.","family":"Desper","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christopher J.","family":"Levy","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,6,2]]},"reference":[{"key":"hb7682_bb1","unstructured":"Bruker (2016). 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