{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:27Z","timestamp":1740174567307,"version":"3.37.3"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2017,7,13]],"date-time":"2017-07-13T00:00:00Z","timestamp":1499904000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,7,13]],"date-time":"2017-07-13T00:00:00Z","timestamp":1499904000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,8,1]]},"abstract":"<jats:p>The title compound, {[Zn(C<jats:sub>9<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b70.5C<jats:sub>6<\/jats:sub>H<jats:sub>7<\/jats:sub>N}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, comprises two independent, but chemically similar, Zn[S<jats:sub>2<\/jats:sub>CN(Et)CH<jats:sub>2<\/jats:sub>py]<jats:sub>2<\/jats:sub> residues and a 4-methylpyridine solvent molecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one dithiocarbamate ligand bridging in a \u03bc<jats:sub>2<\/jats:sub>-\u03ba<jats:sup>3<\/jats:sup> mode, employing one pyridyl N and both dithiocarbamate S atoms, while the other is \u03ba<jats:sup>2<\/jats:sup>-chelating. In each case, the resultant ZnNS<jats:sub>4<\/jats:sub> coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C\u2014H...S, methylene-C\u2014H...N(pyridyl) and pyridyl-C\u2014H...\u03c0(ZnS<jats:sub>2<\/jats:sub>C) interactions. The connection between the chain and the 4-methylpyridine solvent molecule is of the type pyridyl-C\u2014H...N(4-methylpyridine).<\/jats:p>","DOI":"10.1107\/s2056989017010179","type":"journal-article","created":{"date-parts":[[2017,7,12]],"date-time":"2017-07-12T15:29:13Z","timestamp":1499873353000},"page":"1162-1166","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A one-dimensional coordination polymer, <i>catena<\/i>-poly[[[[<i>N<\/i>-ethyl-<i>N<\/i>-(pyridin-4-ylmethyl)dithiocarbamato-\u03ba<sup>2<\/sup>\n                  <i>S<\/i>,<i>S<\/i>\u2032]zinc(II)]-\u03bc<sub>2<\/sub>-<i>N<\/i>-ethyl-<i>N<\/i>-(pyridin-4-ylmethyl)dithiocarbamato-\u03ba<sup>3<\/sup>\n                  <i>S<\/i>,<i>S<\/i>\u2032:<i>N<\/i>] 4-methylpyridine hemisolvate]"],"prefix":"10.1107","volume":"73","author":[{"given":"Pavel","family":"Poplaukhin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hadi D.","family":"Arman","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. T.","family":"Tiekink","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,7,13]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/hb7691\/hb7691.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/hb7691\/hb7691.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:20:16Z","timestamp":1736763616000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989017010179"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,13]]},"references-count":0,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2017,8]]}},"alternative-id":["S2056989017010179"],"URL":"https:\/\/doi.org\/10.1107\/s2056989017010179","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2017,7,13]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb7691","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"6 July 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"8 July 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 July 2017","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb7691"}},{"value":"\u00a9 2017 Poplaukhin et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}