{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:27Z","timestamp":1740174567103,"version":"3.37.3"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2017,7,18]],"date-time":"2017-07-18T00:00:00Z","timestamp":1500336000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,7,18]],"date-time":"2017-07-18T00:00:00Z","timestamp":1500336000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003443","name":"Ministry of Education and Science of the Russian Federation","doi-asserted-by":"crossref","award":["4.5388.2017\/8.9"],"award-info":[{"award-number":["4.5388.2017\/8.9"]}],"id":[{"id":"10.13039\/501100003443","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100003443","name":"Ministry of Education and Science of the Russian Federation","doi-asserted-by":"crossref","award":["02.a03.21.0008"],"award-info":[{"award-number":["02.a03.21.0008"]}],"id":[{"id":"10.13039\/501100003443","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,8,1]]},"abstract":"<jats:p>The title compound, [Zn(C<jats:sub>20<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>4<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b72.5CH<jats:sub>3<\/jats:sub>OH, <jats:bold>I<\/jats:bold>, was synthesized <jats:italic>via<\/jats:italic> the reaction of zinc acetate with the respective ligand and isolated as a methanol solvate, <jats:italic>i.e.<\/jats:italic>, as <jats:bold>I\u00b72.5CH<jats:sub>3<\/jats:sub>OH<\/jats:bold>. The crystal structure is triclinic (space group <jats:italic>P<\/jats:italic>-1), with two complex molecules (<jats:italic>\n                     <jats:bold>A<\/jats:bold>\n                  <\/jats:italic> and <jats:italic>\n                     <jats:bold>B<\/jats:bold>\n                  <\/jats:italic>) and five methanol solvent molecules in the asymmetric unit. One of the five methanol solvent molecules is disordered over two sets of sites, with an occupancy ratio of 0.75:0.25. Molecules <jats:italic>\n                     <jats:bold>A<\/jats:bold>\n                  <\/jats:italic> and <jats:italic>\n                     <jats:bold>B<\/jats:bold>\n                  <\/jats:italic> are conformers and distinguished by the conformations of the bidentate 1-phenyl-3-methyl-4-[(quinolin-3-yl)iminomethyl]-1<jats:italic>H<\/jats:italic>-pyrazol-5-olate ligands. In both molecules, the zinc cations have distorted tetrahedral coordination spheres, binding the monoanionic ligands through the pyrazololate O and imine N atoms. The two ligands adopt slightly different conformations in terms of the orientation of the terminal phenyl and quinoline substituents with respect to the central pyrazololate moiety. The molecular geometries of <jats:italic>\n                     <jats:bold>A<\/jats:bold>\n                  <\/jats:italic> and <jats:italic>\n                     <jats:bold>B<\/jats:bold>\n                  <\/jats:italic> are supported by intramolecular C\u2014H...O and C\u2014H...N hydrogen bonds. In the crystal of <jats:bold>I<\/jats:bold>, molecules form dimers both by secondary intermolecular Zn...O [3.140\u2005(2)\u20133.553\u2005(3)\u2005\u00c5] and \u03c0\u2013\u03c0 stacking interactions. The dimers are linked by intermolecular hydrogen bonds through the solvent methanol molecules into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989017010441","type":"journal-article","created":{"date-parts":[[2017,7,18]],"date-time":"2017-07-18T09:18:31Z","timestamp":1500369511000},"page":"1208-1212","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of bis{1-phenyl-3-methyl-4-[(quinolin-3-yl)iminomethyl-\u03ba<i>N<\/i>]-1<i>H<\/i>-pyrazol-5-olato-\u03ba<i>O<\/i>}zinc methanol 2.5-solvate from synchrotron X-ray diffraction"],"prefix":"10.1107","volume":"73","author":[{"given":"Anatoliy S.","family":"Burlov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Valery G.","family":"Vlasenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pavel V.","family":"Dorovatovskii","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2266-8944","authenticated-orcid":true,"given":"Yan V.","family":"Zubavichus","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8806-2975","authenticated-orcid":true,"given":"Victor N.","family":"Khrustalev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,7,18]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/wm5401\/wm5401.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/wm5401\/wm5401.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:20:22Z","timestamp":1736763622000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989017010441"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,18]]},"references-count":0,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2017,8]]}},"alternative-id":["S2056989017010441"],"URL":"https:\/\/doi.org\/10.1107\/s2056989017010441","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2017,7,18]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5401","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"27 June 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 July 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"18 July 2017","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5401"}},{"value":"\u00a9 2017 Burlov et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}