{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T17:54:34Z","timestamp":1774547674481,"version":"3.50.1"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2017,7,21]],"date-time":"2017-07-21T00:00:00Z","timestamp":1500595200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,7,21]],"date-time":"2017-07-21T00:00:00Z","timestamp":1500595200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,8,1]]},"abstract":"<jats:p>The common structural feature of the title compounds, [Zn(C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>NOS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)]\u00b7C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N (I) and [Zn(C<jats:sub>5<\/jats:sub>H<jats:sub>10<\/jats:sub>NOS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)]\u00b7C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N (II), which differ by having dithiocarbamate N-bound methyl (I) and ethyl (II) groups, is the coordination of each Zn<jats:sup>II<\/jats:sup> atom by two non-symmetrically chelating dithiocarbamate ligands and by a pyridine ligand; in each case, the non-coordinating pyridine molecule is connected to the Zn-containing molecule <jats:italic>via<\/jats:italic> a (hydroxy)O\u2014H...N(pyridine) hydrogen bond. The resulting NS<jats:sub>4<\/jats:sub> coordination geometry is closer to a square-pyramid than a trigonal bipyramid in the case of (I), but almost intermediate between the two extremes in (II). The molecular packing features (hydroxy)O\u2014H...O(hydroxy) hydrogen bonds, leading to supramolecular chains with a zigzag arrangement along [10-1] (I) or a helical arrangement along [010] (II). In (I), \u03c0\u2013\u03c0 [inter-centroid distances = 3.4738\u2005(10) and 3.4848\u2005(10)\u2005\u00c5] between coordinating and non-coordinating pyridine molecules lead to stacks comprising alternating rings along the <jats:italic>a<\/jats:italic> axis. In (II), weaker \u03c0\u2013\u03c0 contacts occur between centrosymmetrically related pairs of coordinating pyridine molecules [inter-centroid separation = 3.9815\u2005(14)\u2005\u00c5]. Further interactions, including C\u2014H...\u03c0(chelate) interactions in (I), lead to a three-dimensional architecture in each case.<\/jats:p>","DOI":"10.1107\/s2056989017010568","type":"journal-article","created":{"date-parts":[[2017,7,21]],"date-time":"2017-07-21T09:36:36Z","timestamp":1500629796000},"page":"1246-1251","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Crystal structure of bis[<i>N<\/i>-(2-hydroxyethyl)-<i>N<\/i>-methyldithiocarbamato-\u03ba<sup>2<\/sup>\n                  <i>S<\/i>,<i>S<\/i>\u2032](pyridine)zinc(II) pyridine monosolvate and its <i>N<\/i>-ethyl analogue"],"prefix":"10.1107","volume":"73","author":[{"given":"Pavel","family":"Poplaukhin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. T.","family":"Tiekink","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,7,21]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/wm5406\/wm5406.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2017\/08\/00\/wm5406\/wm5406.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:20:37Z","timestamp":1736763637000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989017010568"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,21]]},"references-count":0,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2017,8]]}},"alternative-id":["S2056989017010568"],"URL":"https:\/\/doi.org\/10.1107\/s2056989017010568","relation":{},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,7,21]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5406","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"13 July 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 July 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 July 2017","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5406"}},{"value":"\u00a9 2017 Poplaukhin and Tiekink","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}