{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,9]],"date-time":"2026-04-09T18:20:50Z","timestamp":1775758850348,"version":"3.50.1"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2017,8,21]],"date-time":"2017-08-21T00:00:00Z","timestamp":1503273600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,8,21]],"date-time":"2017-08-21T00:00:00Z","timestamp":1503273600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"name":"North-West University, South Africa"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,9,1]]},"abstract":"<jats:p>The title compound, [Cd<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>10<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>], is a neutral dinuclear cadmium(II) complex bearing four bis<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-diallyldithiocarbamate ligands coordinating to two Cd<jats:sup>II<\/jats:sup>cations. In each of the monomeric subunits, there are four S atoms of two dithiocarbamate ligands [Cd\u2014S = 2.5558\u2005(3), 2.8016\u2005(3), 2.6050\u2005(3) and 2.5709\u2005(3)\u2005\u00c5] that coordinate to one Cd<jats:sup>II<\/jats:sup>atom in a bidentate mode. The dimers are located over an inversion centre bridged by two additional bridging Cd\u2014S bonds [2.6021\u2005(3)\u2005\u00c5], leading to a substantial distortion of the geometry of the monomeric subunit from the expected square-planar geometry. The five-coordinate environment around each of the Cd<jats:sup>II<\/jats:sup>ions in the dimer is best described as substantially tetragonally distorted square pyramidal. The dithiocarbamate groups are themselves planar and are also coplanar with the Cd<jats:sup>II<\/jats:sup>ions. The negative charge on these groups is delocalized by resonance across the S atoms bound to the Cd<jats:sup>II<\/jats:sup>cation. This delocalization of the \u03c0 electrons in the dithiocarbamate groups also extends to the C\u2014N bonds as they reveal significant double bond character [C\u2014N = 1.3213\u2005(16) and 1.3333\u2005(15)\u2005\u00c5].<\/jats:p>","DOI":"10.1107\/s2056989017011616","type":"journal-article","created":{"date-parts":[[2017,8,22]],"date-time":"2017-08-22T08:21:44Z","timestamp":1503390104000},"page":"1353-1356","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Bis(\u03bc-<i>N<\/i>,<i>N<\/i>-diallyldithiocarbamato)bis[(<i>N<\/i>,<i>N<\/i>-diallyldithiocarbamato)cadmium]"],"prefix":"10.1107","volume":"73","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2689-3981","authenticated-orcid":true,"given":"Damian C.","family":"Onwudiwe","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3221-0235","authenticated-orcid":true,"given":"Madalina","family":"Hrubaru","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eric C.","family":"Hosten","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6617-1011","authenticated-orcid":true,"given":"Charmaine","family":"Arderne","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,8,21]]},"reference":[{"key":"zl2710_bb1","unstructured":"Bruker (2009). 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