{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:28Z","timestamp":1740174568176,"version":"3.37.3"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2017,8,21]],"date-time":"2017-08-21T00:00:00Z","timestamp":1503273600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,8,21]],"date-time":"2017-08-21T00:00:00Z","timestamp":1503273600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,9,1]]},"abstract":"<jats:p>The full molecule of the binuclear title compound, [Cd<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>6<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>], is generated by the application of a centre of inversion located at the middle of the central CH<jats:sub>2<\/jats:sub>\u2014CH<jats:sub>2<\/jats:sub>bond of the adipate dianion; the latter chelates a Cd<jats:sup>II<\/jats:sup>atom at each end. Along with two carboxylate-O atoms, the Cd<jats:sup>II<\/jats:sup>ion is coordinated by the two N atoms of the chelating benzene-1,2-diamine ligand, a Cl<jats:sup>\u2212<\/jats:sup>anion and an aqua ligand to define a distorted octahedral CdClN<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>coordination geometry with the monodentate ligands being mutually<jats:italic>cis<\/jats:italic>. The disparity in the Cd\u2014N bond lengths is related to the relative<jats:italic>trans<\/jats:italic>effect exerted by the Cd\u2014O bonds formed by the carboxylate-O and aqua-O atoms. The packing features water-O\u2014H...O(carboxylate) and benzene-1,2-diamine-N\u2014H...Cl hydrogen bonds, leading to layers that stack along the<jats:italic>a<\/jats:italic>-axis direction. The lack of directional interactions between the layers is confirmed by a Hirshfeld surface analysis.<\/jats:p>","DOI":"10.1107\/s2056989017011677","type":"journal-article","created":{"date-parts":[[2017,8,22]],"date-time":"2017-08-22T08:21:44Z","timestamp":1503390104000},"page":"1363-1367","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["(\u03bc<sub>2<\/sub>-Adipato-\u03ba<sup>4<\/sup><i>O<\/i>,<i>O<\/i>\u2032:<i>O<\/i>\u2032\u2032,<i>O<\/i>\u2032\u2032\u2032)bis[aqua(benzene-1,2-diamine-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)chloridocadmium]: crystal structure and Hirshfeld surface analysis"],"prefix":"10.1107","volume":"73","author":[{"given":"Wannur Sofiasalamah Khairiah A.","family":"Rahman","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J.","family":"Ahmad","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Siti Nadiah Abdul","family":"Halim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mukesh M.","family":"Jotani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. 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