{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:29Z","timestamp":1740174569175,"version":"3.37.3"},"reference-count":30,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2017,9,12]],"date-time":"2017-09-12T00:00:00Z","timestamp":1505174400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,9,12]],"date-time":"2017-09-12T00:00:00Z","timestamp":1505174400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,10,1]]},"abstract":"<jats:p>Reaction of 2 equiv. of the lithium carboranylamidinate Li[<jats:italic>o<\/jats:italic>-(C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>B<jats:sub>10<\/jats:sub>)C(NCy)(NHCy)] with SnCl<jats:sub>2<\/jats:sub>in THF afforded the stannylene compound bis(<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-dicyclohexylamidinatocarboranate)tin(II), Sn<jats:sup>II<\/jats:sup>[<jats:italic>o<\/jats:italic>-(C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>B<jats:sub>10<\/jats:sub>)C(NCy)(NHCy)]<jats:sub>2<\/jats:sub>(<jats:bold>1<\/jats:bold>). A similar reaction of SnCl<jats:sub>4<\/jats:sub>with 2 equiv. of Li[<jats:italic>o<\/jats:italic>-(C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>B<jats:sub>10<\/jats:sub>)C(N<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>Pr)(NH<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>Pr)] unexpectedly afforded the known solvated pentachloridostannate(IV) salt [Li(THF)<jats:sub>4<\/jats:sub>][SnCl<jats:sub>5<\/jats:sub>(THF)] as the main reaction product. Small amounts of the new chlorido-tin(IV) bis(carboranylamidinate) bis(<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-diisopropylamidinatocarboranate)chloridotin(IV), Sn<jats:sup>IV<\/jats:sup>Cl[<jats:italic>o<\/jats:italic>-(C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>B<jats:sub>10<\/jats:sub>)C(N<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>Pr)(NH<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>Pr)][<jats:italic>o<\/jats:italic>-(C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>B<jats:sub>10<\/jats:sub>)C(N<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>Pr)<jats:sub>2<\/jats:sub>] (<jats:bold>2<\/jats:bold>), were isolated as a by-product. Single-crystal X-ray structure analysis revealed a<jats:italic>\u03baC<\/jats:italic>,<jats:italic>\u03baN<\/jats:italic>-chelating coordination of the carboranylamidinate ligands in both<jats:bold>1<\/jats:bold>and<jats:bold>2<\/jats:bold>. The Sn atom in<jats:bold>1<\/jats:bold>adopts a pseudo-trigonal\u2013bipyramidal coordination under participation of a stereoactive lone pair. In<jats:bold>2<\/jats:bold>, a trigonal\u2013bipyramidal coordination of Sn is completed by a chlorido ligand.<\/jats:p>","DOI":"10.1107\/s2056989017012671","type":"journal-article","created":{"date-parts":[[2017,9,12]],"date-time":"2017-09-12T08:32:24Z","timestamp":1505205144000},"page":"1443-1448","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and crystal structures of two new tin bis(carboranylamidinate) complexes"],"prefix":"10.1107","volume":"73","author":[{"given":"Nicole","family":"Harmgarth","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4660-1691","authenticated-orcid":true,"given":"Phil","family":"Liebing","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Philipp","family":"Hillebrand","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sabine","family":"Busse","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5209-0018","authenticated-orcid":true,"given":"Frank T.","family":"Edelmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,9,12]]},"reference":[{"key":"zl2714_bb1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1107\/S0021889898007717","volume":"32","author":"Altomare","year":"1999","journal-title":"J. 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