{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:28Z","timestamp":1740174568996,"version":"3.37.3"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2017,9,15]],"date-time":"2017-09-15T00:00:00Z","timestamp":1505433600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,9,15]],"date-time":"2017-09-15T00:00:00Z","timestamp":1505433600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,10,1]]},"abstract":"<jats:p>In the title compound, [Zn(C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>NOS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>4<\/jats:sub>)], the Zn<jats:sup>II<\/jats:sup>atom exists within a NS<jats:sub>4<\/jats:sub>donor set defined by two chelating dithiocarbamate ligands and a pyridyl-<jats:italic>N<\/jats:italic>atom derived from a terminally bound 4-pyridinealdazine ligand. The distorted coordination geometry tends towards square-pyramidal with the pyridyl-N atom occupying the apical position. In the crystal, hydroxyl-O\u2014H...O(hydroxyl) and hydroxyl-O\u2014H...N(pyridyl) hydrogen-bonding give rise to a supramolecular double-chain along [1-10]; methyl-C\u2014H...\u03c0(chelate ring) interactions help to consolidate the chain. The chains are connected into a three-dimensional architecture<jats:italic>via<\/jats:italic>pyridyl-C\u2014H...O(hydroxyl) interactions. In addition to the contacts mentioned above, the Hirshfeld surface analysis points to the significance of relatively weak \u03c0\u2013\u03c0 interactions between pyridyl rings [inter-centroid distance = 3.901\u2005(3)\u2005\u00c5].<\/jats:p>","DOI":"10.1107\/s2056989017012725","type":"journal-article","created":{"date-parts":[[2017,9,15]],"date-time":"2017-09-15T08:12:19Z","timestamp":1505463139000},"page":"1458-1464","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Bis[<i>N<\/i>-2-hydroxyethyl,<i>N<\/i>-methyldithiocarbamato-\u03ba<sup>2<\/sup><i>S<\/i>,<i>S<\/i>)'-4-{[(pyridin-4-ylmethylidene)hydrazinylidene}methyl]pyridine-\u03ba<i>N<\/i><sup>1<\/sup>)zinc(II): crystal structure and Hirshfeld surface analysis"],"prefix":"10.1107","volume":"73","author":[{"given":"Grant A.","family":"Broker","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mukesh M.","family":"Jotani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. 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