{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T20:34:45Z","timestamp":1778704485756,"version":"3.51.4"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2017,9,19]],"date-time":"2017-09-19T00:00:00Z","timestamp":1505779200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,9,19]],"date-time":"2017-09-19T00:00:00Z","timestamp":1505779200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,10,1]]},"abstract":"<jats:p>The title structures, [Zn<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>)]\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO (I) and [Zn<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>14<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>)] (II), each feature a bidentate, bridging bipyridyl-type ligand encompassing a di-amide group. In (I), the binuclear compound is disposed about a centre of inversion, leading to an open conformation, while in (II), the complete molecule is completed by the application of a twofold axis of symmetry so that the bridging ligand has a U-shape. In each of (I) and (II), the dithiocarbamate ligands are chelating with varying degrees of symmetry, so the zinc atom is within an NS<jats:sub>4<\/jats:sub>set approximating a square-pyramid for (I) and a trigonal-bipyramid for (II). The solvent dimethylformaide (DMF) molecules in (I) connect to the bridging ligand<jats:italic>via<\/jats:italic>amide-N\u2014H...O(DMF) and various amide-, DMF-C\u2014H...O(amide, DMF) interactions. The resultant three-molecule aggregates assemble into a three-dimensional architecture<jats:italic>via<\/jats:italic>C\u2014H...\u03c0(pyridyl, chelate ring) interactions. In (II), undulating tapes sustained by amide-N\u2014H...O(amide) hydrogen bonding lead to linear supramolecular chains with alternating molecules lying to either side of the tape; no further directional interactions are noted in the crystal.<\/jats:p>","DOI":"10.1107\/s2056989017012956","type":"journal-article","created":{"date-parts":[[2017,9,19]],"date-time":"2017-09-19T08:36:13Z","timestamp":1505810173000},"page":"1501-1507","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Crystal structures of {\u03bc<sub>2<\/sub>-<i>N<\/i>,<i>N<\/i>\u2032-bis[(pyridin-3-yl)methyl]ethanediamide}tetrakis(dimethylcarbamodithioato)dizinc(II) dimethylformamide disolvate and {\u03bc<sub>2<\/sub>-<i>N<\/i>,<i>N<\/i>\u2032-bis[(pyridin-3-yl)methyl]ethanediamide}tetrakis(di-<i>n<\/i>-propylcarbamodithioato)dizinc(II)"],"prefix":"10.1107","volume":"73","author":[{"given":"Hadi D.","family":"Arman","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pavel","family":"Poplaukhin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. 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