{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:29Z","timestamp":1740174569956,"version":"3.37.3"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T00:00:00Z","timestamp":1506643200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T00:00:00Z","timestamp":1506643200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","award":["1205608","CHE-0619278"],"award-info":[{"award-number":["1205608","CHE-0619278"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,10,1]]},"abstract":"<jats:p>The structure of the title compound, [Zn(C<jats:sub>14<\/jats:sub>H<jats:sub>18<\/jats:sub>N<jats:sub>4<\/jats:sub>)(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>N)(H<jats:sub>2<\/jats:sub>O)](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>, contains a six-coordinate cation consisting of the tetradentate bispicen ligand, coordinated water, and coordinated acetonitrile, with the latter two ligands adopting a<jats:italic>cis<\/jats:italic>configuration. There are two formula units in the asymmetric unit. Both cations show almost identical structural features with the bispicen ligand adopting the more common<jats:italic>cis<\/jats:italic>-\u03b2 conformation. One of the four perchlorate anions is disordered over two positions, with occupancies of 0.9090\u2005(15) and 0.0910\u2005(15). There is extensive inter-ionic hydrogen bonding between the perchlorate anions and O\u2014H and N\u2014H groups in the cations, including a bifurcated hydrogen bond between an N\u2014H group and two O atoms of one perchlorate anion. As a result of this extended hydrogen-bond network, the ions are linked into a complex three-dimensional array.<\/jats:p>","DOI":"10.1107\/s2056989017013603","type":"journal-article","created":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T11:01:05Z","timestamp":1506682865000},"page":"1568-1571","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(Acetonitrile-\u03ba<i>N<\/i>)aqua[<i>N<\/i>,<i>N<\/i>\u2032-bis(pyridin-2-ylmethyl)ethane-1,2-diamine-\u03ba<sup>4<\/sup><i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032,<i>N<\/i>\u2032\u2032\u2032]zinc(II) perchlorate"],"prefix":"10.1107","volume":"73","author":[{"given":"Ugochukwu","family":"Okeke","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yilma","family":"Gultneh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2770-7076","authenticated-orcid":true,"given":"Ray J.","family":"Butcher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,9,29]]},"reference":[{"key":"im2479_bb1","unstructured":"Bruker (2002). 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