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The<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032-donating imine ligand led to a mononuclear compound, namely dichlorido[<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethyl-<jats:italic>N<\/jats:italic>\u2032-(pyridin-2-ylmethylidene)ethane-1,2-diamine]copper(II) monohydrate, [CuCl<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>3<\/jats:sub>)]\u00b7H<jats:sub>2<\/jats:sub>O,<jats:bold>1<\/jats:bold>, while the<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>O<\/jats:italic>-donating imine ligand produced a binuclear metal complex, namely \u03bc<jats:sub>2<\/jats:sub>-chlorido-dichlorido(\u03bc<jats:sub>2<\/jats:sub>-2-{[2-(dimethylamino)ethyl]iminomethyl}phenolato)(<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylethylenediamine)dicopper(II) 0.11-hydrate, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>11<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>2<\/jats:sub>O)Cl<jats:sub>3<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>)]\u00b70.11H<jats:sub>2<\/jats:sub>O,<jats:bold>2<\/jats:bold>. The structure of<jats:bold>2<\/jats:bold>is a remarkable example of a binuclear copper(II) complex containing a single substituted 2-iminomethylphenolate ligand that has two copper(II) sites in square-pyramidal coordination.<\/jats:p>","DOI":"10.1107\/s2056989017013652","type":"journal-article","created":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T11:01:05Z","timestamp":1506682865000},"page":"1563-1567","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["<i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032<i>versus N<\/i>,<i>N<\/i>\u2032,<i>O<\/i>imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu<sup>II<\/sup>compounds"],"prefix":"10.1107","volume":"73","author":[{"given":"Raphael Enoque","family":"Ferraz de Paiva","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Douglas Hideki","family":"Nakahata","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marcos Alberto de","family":"Carvalho","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fernando","family":"Rodrigues Goulart Bergamini","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pedro Paulo","family":"Corbi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,9,29]]},"reference":[{"key":"wm5417_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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