{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T12:39:29Z","timestamp":1791549569869,"version":"4.3.4"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2017,10,3]],"date-time":"2017-10-03T00:00:00Z","timestamp":1506988800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,10,3]],"date-time":"2017-10-03T00:00:00Z","timestamp":1506988800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,11,1]]},"abstract":"<jats:p>The title compound, [CdNa<jats:sub>2<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or [CdNa<jats:sub>2<\/jats:sub>(1,3-bdc)<jats:sub>2<\/jats:sub>(DMF)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, is a new Cd<jats:sup>II<\/jats:sup>\u2013Na<jats:sup>I<\/jats:sup>heterobimetallic coordination polymer. The asymmetric unit consists of one Cd<jats:sup>II<\/jats:sup>atom, two Na<jats:sup>I<\/jats:sup>atoms, two 1,3-bdc ligands, two coordinated water molecules and one coordinated DMF molecule. The Cd<jats:sup>II<\/jats:sup>atom exhibits a seven-coordinate geometry, while the Na<jats:sup>I<\/jats:sup>atoms can be considered to be pentacoordinate. The metal ions and their symmetry-related equivalents are connected<jats:italic>via<\/jats:italic>chelating\u2013bridging carboxylate groups of the 1,3-bdc ligands to generate a three-dimensional framework. In the crystal, there are classical O\u2014H...O hydrogen bonds involving the coordinated water molecules and the 1,3-bdc carboxylate groups and \u03c0\u2013\u03c0 stacking between the benzene rings of the 1,3-bdc ligands present within the frameworks.<\/jats:p>","DOI":"10.1107\/s2056989017013871","type":"journal-article","created":{"date-parts":[[2017,10,3]],"date-time":"2017-10-03T08:10:28Z","timestamp":1507018228000},"page":"1599-1602","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of poly[diaquabis(\u03bc<sub>5<\/sub>-benzene-1,3-dicarboxylato)(<i>N<\/i>,<i>N<\/i>-dimethylformamide)cadmium(II)disodium(I)]"],"prefix":"10.1107","volume":"73","author":[{"given":"Matimon","family":"Sangsawang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kittipong","family":"Chainok","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nanthawat","family":"Wannarit","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2017,10,3]]},"reference":[{"key":"pj2046_bb2","doi-asserted-by":"crossref","first-page":"2773","DOI":"10.1021\/cg101534n","volume":"11","author":"Borah","year":"2011","journal-title":"Cryst. 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