{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:30Z","timestamp":1740174570294,"version":"3.37.3"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2017,10,20]],"date-time":"2017-10-20T00:00:00Z","timestamp":1508457600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,10,20]],"date-time":"2017-10-20T00:00:00Z","timestamp":1508457600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100004285","name":"Saint-Petersburg State University","doi-asserted-by":"crossref","award":["0.37.235.2015","3.37.222.2015"],"award-info":[{"award-number":["0.37.235.2015","3.37.222.2015"]}],"id":[{"id":"10.13039\/501100004285","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,11,1]]},"abstract":"<jats:p>The structure of a salt of diprotonated<jats:italic>endo<\/jats:italic>-3-aminotropane crystallized with a copper(II) anionic cluster is reported,<jats:italic>viz.<\/jats:italic>(C<jats:sub>8<\/jats:sub>H<jats:sub>18<\/jats:sub>N<jats:sub>2<\/jats:sub>)[CuCl<jats:sub>3<\/jats:sub>(NO<jats:sub>3<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of intermolecular N\u2014H...O, O\u2014H...Cl and N\u2014H...Cl hydrogen-bonding interactions. Selective crystallization of the title compound can be considered as a simple method for the separation of the<jats:italic>exo<\/jats:italic>and<jats:italic>endo<\/jats:italic>isomers of 3-aminotropane.<\/jats:p>","DOI":"10.1107\/s2056989017014633","type":"journal-article","created":{"date-parts":[[2017,10,20]],"date-time":"2017-10-20T11:41:51Z","timestamp":1508499711000},"page":"1712-1715","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of (1<i>R<\/i>,5<i>S<\/i>)-<i>endo<\/i>-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)"],"prefix":"10.1107","volume":"73","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3183-7594","authenticated-orcid":true,"given":"Sergey N.","family":"Britvin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrey M.","family":"Rumyantsev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,10,20]]},"reference":[{"key":"cq2021_bb1","first-page":"101","volume":"(M)","author":"Begley","year":"1988","journal-title":"J. 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