{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:31Z","timestamp":1740174571598,"version":"3.37.3"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T00:00:00Z","timestamp":1508803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T00:00:00Z","timestamp":1508803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["20871012"],"award-info":[{"award-number":["20871012"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,11,1]]},"abstract":"<jats:p>Two new pentaborates, trisodium zinc cadmium pentaborate, Na<jats:sub>3<\/jats:sub>Zn<jats:sub>0.912<\/jats:sub>Cd<jats:sub>0.088<\/jats:sub>B<jats:sub>5<\/jats:sub>O<jats:sub>10<\/jats:sub>, and trisodium zinc magnesium pentaborate, Na<jats:sub>3<\/jats:sub>Zn<jats:sub>0.845<\/jats:sub>Mg<jats:sub>0.155<\/jats:sub>B<jats:sub>5<\/jats:sub>O<jats:sub>10<\/jats:sub>, have been synthesized by high-temperature solution reactions at 1023\u2005K. Their crystal structures were determined by single-crystal X-ray diffraction. Both solid solutions crystallize in the orthorhombic form of the parent compound Na<jats:sub>3<\/jats:sub>ZnB<jats:sub>5<\/jats:sub>O<jats:sub>10<\/jats:sub>(space group type<jats:italic>Pbca<\/jats:italic>,<jats:italic>Z<\/jats:italic>= 8) and contain the double ring [B<jats:sub>5<\/jats:sub>O<jats:sub>10<\/jats:sub>]<jats:sup>5\u2212<\/jats:sup>anion composed of one BO<jats:sub>4<\/jats:sub>tetrahedron and four BO<jats:sub>3<\/jats:sub>triangles as the basic structural motif. The anions are bridged by tetrahedrally coordinated and occupationally disordered<jats:italic>M<\/jats:italic><jats:sup>2+<\/jats:sup>(<jats:italic>M<\/jats:italic>= Zn\/Cd, Zn\/Mg) cations<jats:italic>via<\/jats:italic>common O atoms to form [<jats:italic>M<\/jats:italic>B<jats:sub>5<\/jats:sub>O<jats:sub>10<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub><jats:sup>3<jats:italic>n<\/jats:italic>\u2212<\/jats:sup>layers. The intralayer intersecting channels and the interlayer voids are occupied by Na<jats:sup>+<\/jats:sup>cations to balance the charge.<\/jats:p>","DOI":"10.1107\/s2056989017015249","type":"journal-article","created":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T08:56:06Z","timestamp":1508835366000},"page":"1774-1778","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structures of the solid solutions Na<sub>3<\/sub>Zn<sub>0.912<\/sub>Cd<sub>0.088<\/sub>B<sub>5<\/sub>O<sub>10<\/sub>and Na<sub>3<\/sub>Zn<sub>0.845<\/sub>Mg<sub>0.155<\/sub>B<sub>5<\/sub>O<sub>10<\/sub>"],"prefix":"10.1107","volume":"73","author":[{"given":"Xue-An","family":"Chen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ya-Hua","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xin-An","family":"Chang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei-Qiang","family":"Xiao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,10,24]]},"reference":[{"key":"wm5422_bb1","doi-asserted-by":"crossref","first-page":"979","DOI":"10.1002\/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO;2-N","volume":"10","author":"Becker","year":"1998","journal-title":"Adv. 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