{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:09Z","timestamp":1736831769612,"version":"3.33.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,3]],"date-time":"2017-11-03T00:00:00Z","timestamp":1509667200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,11,3]],"date-time":"2017-11-03T00:00:00Z","timestamp":1509667200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>The crystal structure of a new supramolecular complex between the tetraphosphonate cavitand 5,11,17,23-tetramethyl-6,10:12,16:18,22:24,4-tetrakis(phenylphosphonato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>\u2032)resorcin(4)arene and the nitrosyl cation NO<jats:sup>+<\/jats:sup>, as the BF<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup>salt, is reported. The complex, of general formula [(C<jats:sub>56<\/jats:sub>H<jats:sub>44<\/jats:sub>P<jats:sub>4<\/jats:sub>O<jats:sub>12<\/jats:sub>)(NO)]BF<jats:sub>4<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>or NO@Tiiii[H, CH<jats:sub>3<\/jats:sub>, C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>] BF<jats:sub>4<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, crystallizes in the space group<jats:italic>P<\/jats:italic>-1. The nitrosyl cation is disordered over two equivalent positions, with occupancies of 0.503\u2005(2) and 0.497\u2005(2), and interacts with two adjacent P=O groups at the upper rim of the cavitand through dipole\u2013charge interactions. In the lattice, the cavitands are connected through a series of C\u2014H...\u03c0 interactions involving the methyl and methylenic H atoms and the aromatic rings of the macrocycle. The structure is further stabilized by the presence of C\u2014H...F interactions between the hydrogen atoms of the cavitands and the F atoms of the tetrafluoridoborate anion. As a result of the disorder, the lattice dichloromethane molecules could not be modelled in terms of atomic sites, and were treated using the<jats:italic>PLATON<\/jats:italic>SQUEEZE procedure [Spek (2015).<jats:italic>Acta Cryst.<\/jats:italic>C<jats:bold>71<\/jats:bold>, 9\u201318]. The complexation process has also been studied in solution through NMR titrations.<\/jats:p>","DOI":"10.1107\/s2056989017015857","type":"journal-article","created":{"date-parts":[[2017,11,3]],"date-time":"2017-11-03T10:05:07Z","timestamp":1509703507000},"page":"1801-1805","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Nitrosonium complexation by the tetraphosphonate cavitand 5,11,17,23-tetramethyl-6,10:12,16:18,22:24,4-tetrakis(phenylphosphonato-\u03ba<sup>2<\/sup><i>O<\/i>,<i>O<\/i>)resorcin(4)arene"],"prefix":"10.1107","volume":"73","author":[{"given":"Roberta","family":"Pinalli","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chiara","family":"Massera","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,11,3]]},"reference":[{"key":"su5400_bb1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1107\/S0021889898007717","volume":"32","author":"Altomare","year":"1999","journal-title":"J. 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