{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T05:20:14Z","timestamp":1768886414519,"version":"3.49.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,17]],"date-time":"2017-11-17T00:00:00Z","timestamp":1510876800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,11,17]],"date-time":"2017-11-17T00:00:00Z","timestamp":1510876800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"crossref","award":["NRF-2015R1D1A3A01020410"],"award-info":[{"award-number":["NRF-2015R1D1A3A01020410"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100002507","name":"Kangwon National University","doi-asserted-by":"crossref","award":["520170312"],"award-info":[{"award-number":["520170312"]}],"id":[{"id":"10.13039\/501100002507","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>The reaction of mercury(II) chloride with bis(pyridin-3-ylmethyl)sulfane (<jats:italic>L<\/jats:italic>, C<jats:sub>12<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>S) in methanol afforded the title crystalline coordination polymer<jats:italic>catena<\/jats:italic>-poly[[dichloridomercury(II)]-\u03bc-bis(pyridin-3-ylmethyl)sulfane-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032], [HgCl<jats:sub>2<\/jats:sub><jats:italic>L<\/jats:italic>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>. The asymmetric unit consists of one Hg<jats:sup>II<\/jats:sup>cation, one<jats:italic>L<\/jats:italic>ligand and two chloride anions. Each Hg<jats:sup>II<\/jats:sup>ion is coordinated by two pyridine N atoms from separate<jats:italic>L<\/jats:italic>ligands and two chloride anions. The metal adopts a highly distorted tetrahedral geometry, with bond angles about the central atom in the range 97.69\u2005(12)\u2013153.86\u2005(7)\u00b0. Each<jats:italic>L<\/jats:italic>ligand bridges two Hg<jats:sup>II<\/jats:sup>ions, forming an infinite \u2013(Hg\u2013<jats:italic>L<\/jats:italic>)<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>\u2013 zigzag chain along the<jats:italic>b<\/jats:italic>axis, with an Hg...Hg separation of 10.3997\u2005(8)\u2005\u00c5. In the crystal, adjacent chains are connected by intermolecular C\u2014H...Cl hydrogen bonds, together with Hg\u2014Cl...\u03c0 interactions [chloride-to-centroid distance = 3.902\u2005(3)\u2005\u00c5], that form between a chloride anion and the one of the pyridine rings of<jats:italic>L<\/jats:italic>, generating a two-dimensional layer extending parallel to (101). These layers are further linked by intermolecular C\u2014H...\u03c0 hydrogen bonds, forming a three-dimensional supramolecular network.<\/jats:p>","DOI":"10.1107\/s205698901701619x","type":"journal-article","created":{"date-parts":[[2017,11,17]],"date-time":"2017-11-17T10:39:39Z","timestamp":1510915179000},"page":"1871-1874","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["A one-dimensional Hg<sup>II<\/sup>coordination polymer based on bis(pyridin-3-ylmethyl)sulfane"],"prefix":"10.1107","volume":"73","author":[{"given":"Suk-Hee","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Youngjin","family":"Kang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ki-Min","family":"Park","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,11,17]]},"reference":[{"key":"sj5541_bb1","unstructured":"Brandenburg, K. 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