{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:32Z","timestamp":1740174572550,"version":"3.37.3"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,21]],"date-time":"2017-11-21T00:00:00Z","timestamp":1511222400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,11,21]],"date-time":"2017-11-21T00:00:00Z","timestamp":1511222400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>We have determined the crystal structures of two decachlorocyclopentasilanes, namely bis(tetra-<jats:italic>n<\/jats:italic>-butylammonium) dichloride decachlorocyclopentasilane dichloromethane disolvate, 2C<jats:sub>16<\/jats:sub>H<jats:sub>36<\/jats:sub>N<jats:sup>+<\/jats:sup>\u00b72Cl<jats:sup>\u2212<\/jats:sup>\u00b7Si<jats:sub>5<\/jats:sub>Cl<jats:sub>10<\/jats:sub>\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (I), and bis(tetraethylammonium) dichloride decachlorocyclopentasilane dichloromethane disolvate, 2C<jats:sub>8<\/jats:sub>H<jats:sub>20<\/jats:sub>N<jats:sup>+<\/jats:sup>\u00b72Cl<jats:sup>\u2212<\/jats:sup>\u00b7Si<jats:sub>5<\/jats:sub>Cl<jats:sub>10<\/jats:sub>\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (II), both of which crystallize with discrete cations, anions, and solvent molecules. In (I), the complete decachlorocyclopentasilane ring is generated by a crystallographic twofold rotation axis. In (II), one cation is located on a general position and the other two are disordered about centres of inversion. These are the first structures featuring the structural motif of a five-membered cyclopentasilane ring coordinated from both sides by a chloride ion. The extended structures of (I) and (II) feature numerous C\u2014H...Cl interactions. In (II), the N atoms are located on centres of inversion and as a result, the ethylene chains are disordered over equally occupied orientations.<\/jats:p>","DOI":"10.1107\/s2056989017016310","type":"journal-article","created":{"date-parts":[[2017,11,21]],"date-time":"2017-11-21T10:17:53Z","timestamp":1511259473000},"page":"1903-1907","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Decachlorocyclopentasilanes coordinated by pairs of chloride anions, with different cations, but the same solvent molecules"],"prefix":"10.1107","volume":"73","author":[{"given":"Maximilian","family":"Moxter","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Julian","family":"Teichmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hans-Wolfram","family":"Lerner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5296-6251","authenticated-orcid":true,"given":"Michael","family":"Bolte","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matthias","family":"Wagner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,11,21]]},"reference":[{"key":"hb7717_bb1","doi-asserted-by":"crossref","first-page":"11188","DOI":"10.1039\/c0dt00925c","volume":"39","author":"Dai","year":"2010","journal-title":"Dalton Trans."},{"key":"hb7717_bb2","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. 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