{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:31Z","timestamp":1740174571969,"version":"3.37.3"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,28]],"date-time":"2017-11-28T00:00:00Z","timestamp":1511827200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2017,11,28]],"date-time":"2017-11-28T00:00:00Z","timestamp":1511827200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002507","name":"Kangwon National University","doi-asserted-by":"crossref","award":["520170523"],"award-info":[{"award-number":["520170523"]}],"id":[{"id":"10.13039\/501100002507","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>The asymmetric unit of the title compound, [Ir(C<jats:sub>17<\/jats:sub>H<jats:sub>11<\/jats:sub>F<jats:sub>2<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>]\u00b70.5CH<jats:sub>3<\/jats:sub>(CH<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>CH<jats:sub>3<\/jats:sub>\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, comprises one Ir<jats:sup>III<\/jats:sup>atom, three 2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl]pyridin-4-yl ligands and half each of an<jats:italic>n<\/jats:italic>-hexane and a dichloromethane solvent molecule located about crystallographic inversion centres. The Ir<jats:sup>III<\/jats:sup>atom displays a distorted octahedral coordination geometry, having three<jats:italic>C<\/jats:italic>,<jats:italic>N<\/jats:italic>-chelating 2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl]pyridin-4-yl ligands arranged in a meridional manner. The Ir<jats:sup>III<\/jats:sup>ion lies almost in the equatorial plane [deviation = 0.0069\u2005(15)\u2005\u00c5]. The average distance [2.041\u2005(3)\u2005\u00c5] of Ir\u2014C bonds is slightly shorter than that [2.076\u2005(3)\u2005\u00c5] of Ir\u2014N bonds. A variety of intra- and intermolecular C\u2014H...F and C\u2014H...\u03c0 hydrogen bonds, as well as intermolecular C\u2014F...\u03c0 interactions, contribute to the stabilization of the molecular and crystal structures, and result in the formation of a two-dimensional network parallel to the<jats:italic>ab<\/jats:italic>plane. No interactions between<jats:italic>n<\/jats:italic>-hexane solvent molecules and the other components in the title compound are observed.<\/jats:p>","DOI":"10.1107\/s2056989017016759","type":"journal-article","created":{"date-parts":[[2017,11,28]],"date-time":"2017-11-28T11:01:36Z","timestamp":1511866896000},"page":"1952-1955","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of<i>mer<\/i>-tris{2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl-\u03ba<i>N<\/i>]pyridin-4-yl-\u03ba<i>C<\/i><sup>4<\/sup>}iridium(III) dichloromethane hemisolvate<i>n<\/i>-hexane hemisolvate"],"prefix":"10.1107","volume":"73","author":[{"given":"Youngjin","family":"Kang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ki-Min","family":"Park","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jinho","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,11,28]]},"reference":[{"key":"hg5501_bb1","unstructured":"Brandenburg, K. 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