{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:32Z","timestamp":1740174572875,"version":"3.37.3"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2018,1,1]],"date-time":"2018-01-01T00:00:00Z","timestamp":1514764800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,1,1]],"date-time":"2018-01-01T00:00:00Z","timestamp":1514764800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,1,1]]},"abstract":"<jats:p>The crystal structure of the title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>18<\/jats:sub>H<jats:sub>12<\/jats:sub>Br<jats:sub>2<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu\u2014O coordination bonds forming chains along the<jats:italic>b<\/jats:italic>axis. The Cu<jats:sup>II<\/jats:sup>ion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry. In the crystal, short S...Br contacts connect neighbouring chains into a two-dimensional network parallel to (101).<\/jats:p>","DOI":"10.1107\/s2056989017017790","type":"journal-article","created":{"date-parts":[[2017,12,15]],"date-time":"2017-12-15T10:01:01Z","timestamp":1513332061000},"page":"38-40","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Bis{\u03bc-2,2\u2032-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-\u03ba<sup>4<\/sup><i>O<\/i>,<i>N<\/i>,<i>N<\/i>\u2032,<i>O<\/i>\u2032}dicopper(II)"],"prefix":"10.1107","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0801-1690","authenticated-orcid":true,"given":"Julia A.","family":"Rusanova","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7680-7279","authenticated-orcid":true,"given":"Dmytro","family":"Bederak","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1834-3020","authenticated-orcid":true,"given":"Vladimir N.","family":"Kokozay","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,1,1]]},"reference":[{"key":"lh5862_bb1","doi-asserted-by":"crossref","first-page":"1487","DOI":"10.1016\/S0277-5387(96)00431-7","volume":"16","author":"Babich","year":"1997","journal-title":"Polyhedron"},{"key":"lh5862_bb2","doi-asserted-by":"crossref","first-page":"559","DOI":"10.1246\/cl.1998.559","volume":"27","author":"Bera","year":"1998","journal-title":"Chem. Lett."},{"key":"lh5862_bb3","unstructured":"Bruker (2008). APEX2, SMART, SAINT and SADABS. Bruker AXS, Inc., Madison, Wisconsin, USA."},{"key":"lh5862_bb4","doi-asserted-by":"crossref","first-page":"4180","DOI":"10.1039\/b414639e","author":"Dhar","year":"2004","journal-title":"Dalton Trans."},{"key":"lh5862_bb5","doi-asserted-by":"crossref","first-page":"344","DOI":"10.1039\/b413410a","author":"Dhar","year":"2005","journal-title":"Dalton Trans."},{"key":"lh5862_bb6","doi-asserted-by":"crossref","first-page":"1891","DOI":"10.1039\/a903403j","volume":"2","author":"Gilbert","year":"1999","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"lh5862_bb7","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"lh5862_bb8","doi-asserted-by":"crossref","first-page":"4742","DOI":"10.1002\/anie.200300573","volume":"42","author":"Jacob","year":"2003","journal-title":"Angew. Chem. Int. Ed."},{"key":"lh5862_bb9","doi-asserted-by":"crossref","first-page":"3735","DOI":"10.1016\/S0277-5387(97)00151-4","volume":"16","author":"Mitra","year":"1997","journal-title":"Polyhedron"},{"key":"lh5862_bb10","doi-asserted-by":"crossref","first-page":"1431","DOI":"10.1039\/b713252b","author":"Nesterova","year":"2008","journal-title":"Dalton Trans."},{"key":"lh5862_bb11","doi-asserted-by":"crossref","first-page":"2131","DOI":"10.1016\/j.jinorgbio.2004.09.020","volume":"98","author":"Prabhakaran","year":"2004","journal-title":"J. Inorg. Biochem."},{"key":"lh5862_bb12","doi-asserted-by":"crossref","first-page":"1797","DOI":"10.1107\/S2056989017015584","volume":"73","author":"Rusanova","year":"2017","journal-title":"Acta Cryst. E"},{"key":"lh5862_bb13","doi-asserted-by":"crossref","first-page":"1610","DOI":"10.1002\/zaac.200600013","volume":"632","author":"Salivon","year":"2006","journal-title":"Z. Anorg. Allg. Chem."},{"key":"lh5862_bb14","doi-asserted-by":"crossref","first-page":"908","DOI":"10.1134\/S1070328407120068","volume":"33","author":"Salivon","year":"2007","journal-title":"Russ. J. Coord. Chem."},{"key":"lh5862_bb15","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"lh5862_bb16","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"lh5862_bb17","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"lh5862_bb18","doi-asserted-by":"crossref","first-page":"949","DOI":"10.1039\/b101883n","volume":"25","author":"Vinogradova","year":"2001","journal-title":"New J. Chem."},{"key":"lh5862_bb19","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"lh5862_bb20","first-page":"823","volume":"5","author":"Xia","year":"2008","journal-title":"Chin. J. Inorg. Chem."},{"key":"lh5862_bb21","doi-asserted-by":"crossref","first-page":"3697","DOI":"10.1080\/00958972.2010.518760","volume":"63","author":"Zhang","year":"2010","journal-title":"J. Coord. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/01\/00\/lh5862\/lh5862.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/01\/00\/lh5862\/lh5862.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:31:29Z","timestamp":1736764289000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989017017790"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,1,1]]},"references-count":21,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2018,1]]}},"alternative-id":["S2056989017017790"],"URL":"https:\/\/doi.org\/10.1107\/s2056989017017790","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2018,1,1]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?lh5862","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"11 November 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 December 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"1 January 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?lh5862"}},{"value":"\u00a9 2018 Rusanovaet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}