{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:33Z","timestamp":1740174573226,"version":"3.37.3"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T00:00:00Z","timestamp":1515715200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T00:00:00Z","timestamp":1515715200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","award":["NA 720\/5--2"],"award-info":[{"award-number":["NA 720\/5--2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,2,1]]},"abstract":"<jats:p>Reaction of Co(NCS)<jats:sub>2<\/jats:sub> and Zn(NCS)<jats:sub>2<\/jats:sub> with 4-pyridinethioamide led to the formation of compounds with composition [Co(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>2<\/jats:sub>S)<jats:sub>4<\/jats:sub>]\u00b7H<jats:sub>2<\/jats:sub>O (<jats:bold>1<\/jats:bold>) and [Zn(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub>] (<jats:bold>2<\/jats:bold>), respectively. The asymmetric unit of compound <jats:bold>1<\/jats:bold>, consists of one cobalt(II) cation, two thiocyanate anions, four 4-pyridinethioamide ligands and one water molecule whereas that of compound <jats:bold>2<\/jats:bold> comprises one zinc(II) cation that is located on a twofold rotation axis as well as one thiocyanate anion and one 4-pyridinethioamide ligand in general positions. In the structure of compound <jats:bold>1<\/jats:bold>, the cobalt(II) cations are octahedrally coordinated by two terminal N-bonding thiocyanate anions and by the N atoms of four 4-pyridinethioamide ligands, resulting in discrete and slightly distorted octahedral complexes. These complexes are linked into a three-dimensional network <jats:italic>via<\/jats:italic> intermolecular N\u2014H...S hydrogen bonding between the amino H atoms and the thiocyanate S atoms. From this arrangement, channels are formed in which the water molecules are embedded and linked to the host structure by intermolecular O\u2014H...S and N\u2014H...O hydrogen bonding. In the structure of compound <jats:bold>2<\/jats:bold>, the zinc(II) cations are tetrahedrally coordinated by two N-bonding thiocyanate anions and the N atoms of two 4-pyridinethioamide ligands into discrete complexes. These complexes are likewise connected into a three-dimensional network by intermolecular N\u2014H...S hydrogen bonding between the amino H atoms and the thioamide S atoms.<\/jats:p>","DOI":"10.1107\/s205698901800021x","type":"journal-article","created":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T09:33:33Z","timestamp":1515749613000},"page":"141-146","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structures of tetrakis(pyridine-4-thioamide-\u03ba<i>N<\/i>)bis(thiocyanato-\u03ba<i>N<\/i>)cobalt(II) monohydrate and bis(pyridine-4-thioamide-\u03ba<i>N<\/i>)bis(thiocyanato-\u03ba<i>N<\/i>)zinc(II)"],"prefix":"10.1107","volume":"74","author":[{"given":"Tristan","family":"Neumann","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,1,12]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/02\/00\/wm5430\/wm5430.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/02\/00\/wm5430\/wm5430.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:59:34Z","timestamp":1736765974000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S205698901800021X"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,1,12]]},"references-count":0,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2018,2]]}},"alternative-id":["S205698901800021X"],"URL":"https:\/\/doi.org\/10.1107\/s205698901800021x","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2018,1,12]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5430","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"13 December 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 January 2018","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 January 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5430"}},{"value":"\u00a9 2018 Neumann et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}