{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T15:25:31Z","timestamp":1753889131537,"version":"3.37.3"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2018,1,26]],"date-time":"2018-01-26T00:00:00Z","timestamp":1516924800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,1,26]],"date-time":"2018-01-26T00:00:00Z","timestamp":1516924800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,2,1]]},"abstract":"<jats:p>A new heterometallic Cu<jats:sup>I<\/jats:sup>\u2013Ni<jats:sup>II<\/jats:sup> coordination polymer, poly[[tetra-\u03bc<jats:sub>3<\/jats:sub>-iodido-\u03bc<jats:sub>2<\/jats:sub>-iodido-bis(\u03bc<jats:sub>3<\/jats:sub>-piperidine-1-dithiocarbamato)propionitrilepentacopper(I)nickel(II)] chloroform monosolvate], {[Cu<jats:sup>I<\/jats:sup>\n                  <jats:sub>5<\/jats:sub>Ni<jats:sup>II<\/jats:sup>I<jats:sub>5<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>10<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>N)]\u00b7CHCl<jats:sub>3<\/jats:sub>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, has been synthesized and structurally characterized. This coordination polymer consists of an Ni<jats:sup>II<\/jats:sup> mononuclear unit of Ni<jats:sup>II<\/jats:sup>(Pip-dtc)<jats:sub>2<\/jats:sub> (Pip-dtc<jats:sup>\u2212<\/jats:sup> is piperidine-1-dithiocarbamate) and a pentanuclear copper(I) cluster unit of Cu<jats:sub>5<\/jats:sub>I<jats:sub>5<\/jats:sub>(CH<jats:sub>3<\/jats:sub>CH<jats:sub>2<\/jats:sub>CN). The Ni<jats:sup>II<\/jats:sup> ion, which lies on an inversion centre, is surrounded by four S atoms in a square-planar coordination geometry while all Cu<jats:sup>I<\/jats:sup> ions have distorted tetrahedral coordination geometries. In the pentanuclear copper(I) cluster unit, a mirror plane passes through one Cu<jats:sup>I<\/jats:sup> ion and three I ions. All the S atoms in Ni<jats:sup>II<\/jats:sup>(Pip-dtc) are also coordinated by the Cu<jats:sup>I<\/jats:sup> ions, forming an infinite zigzag chain structure along the <jats:italic>b-<\/jats:italic>axis direction. The chains are weakly connected by solvent CHCl<jats:sub>3<\/jats:sub> molecules <jats:italic>via<\/jats:italic> Cl...I [3.653\u2005(1)\u2005\u00c5] and Cl...S [3.4370\u2005(1)\u2005\u00c5] short-contact interactions.<\/jats:p>","DOI":"10.1107\/s2056989018000750","type":"journal-article","created":{"date-parts":[[2018,1,29]],"date-time":"2018-01-29T10:39:47Z","timestamp":1517222387000},"page":"233-236","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of a new mixed-metal coordination polymer consisting of Ni<sup>II<\/sup> piperidine-dithiocarbamate and pentanuclear Cu<sup>I<\/sup>\u2014I cluster units"],"prefix":"10.1107","volume":"74","author":[{"given":"Kento","family":"Himoto","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Toshiya","family":"Horii","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shoki","family":"Oda","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shimpei","family":"Suzuki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kunihisa","family":"Sugimoto","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3430-9498","authenticated-orcid":true,"given":"Takashi","family":"Okubo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2546-2602","authenticated-orcid":true,"given":"Masahiko","family":"Maekawa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takayoshi","family":"Kuroda-Sowa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,1,26]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/02\/00\/is5484\/is5484.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/02\/00\/is5484\/is5484.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:00:02Z","timestamp":1736766002000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989018000750"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,1,26]]},"references-count":0,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2018,2]]}},"alternative-id":["S2056989018000750"],"URL":"https:\/\/doi.org\/10.1107\/s2056989018000750","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2018,1,26]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?is5484","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"15 December 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 January 2018","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"26 January 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?is5484"}},{"value":"\u00a9 2018 Himoto et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}