{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,1]],"date-time":"2026-05-01T02:31:53Z","timestamp":1777602713659,"version":"3.51.4"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2018,2,13]],"date-time":"2018-02-13T00:00:00Z","timestamp":1518480000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,2,13]],"date-time":"2018-02-13T00:00:00Z","timestamp":1518480000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"crossref","award":["2016M602712"],"award-info":[{"award-number":["2016M602712"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"crossref","award":["2015M582573"],"award-info":[{"award-number":["2015M582573"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,3,1]]},"abstract":"<jats:p>The title compound,, [Fe<jats:sub>4<\/jats:sub>Ni(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>14<\/jats:sub>S<jats:sub>4<\/jats:sub>)(CO)<jats:sub>10<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, is reported as a biomimic model for the active site of [FeFe]-hydrogenases. Bis(2-mercaptoethyl)-1,3-propanedithio ether nickel(II) was firstly introduced into [Fe<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>S<jats:sub>2<\/jats:sub>)(CO)<jats:sub>5<\/jats:sub>] as an S-containing ligand. It coordinates with two [Fe<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>S<jats:sub>2<\/jats:sub>)(CO)<jats:sub>5<\/jats:sub>] groups, and a five-metal core complex is formed. The Fe<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>core is in a butterfly conformation. The Fe\u2014Fe distances in the [Fe<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>S<jats:sub>2<\/jats:sub>)(CO)<jats:sub>5<\/jats:sub>] groups are 2.5126\u2005(6) and 2.5086\u2005(7)\u2005\u00c5. The distances between the adjacent Fe and Ni atoms are 3.5322\u2005(1) and 3.5143\u2005(1)\u2005\u00c5. There are intramolecular C\u2014H...O and C\u2014H...S contacts present in the complex. In the crystal, the five metal cores are linked<jats:italic>via<\/jats:italic>C\u2014H...O hydrogen bonds, forming columns lying parallel to (110). The dichloromethane solvent molecules are each partially disordered over two positions and only one is linked to the five-metal core complex by a C\u2014H...O hydrogen bond.<\/jats:p>","DOI":"10.1107\/s2056989018001731","type":"journal-article","created":{"date-parts":[[2018,2,13]],"date-time":"2018-02-13T09:37:22Z","timestamp":1518514642000},"page":"328-331","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of decacarbonyl(\u03bc<sub>3<\/sub>-3,7-dithianonane-1,9-dithiolato)bis(\u03bc<sub>2<\/sub>-propane-1,3-dithiolato)nickel(II)tetrairon(II) dichloromethane disolvate"],"prefix":"10.1107","volume":"74","author":[{"given":"Gan","family":"Ren","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ge","family":"Sang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,2,13]]},"reference":[{"key":"su5420_bb1","unstructured":"Bruker (2007). APEX2, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"su5420_bb2","doi-asserted-by":"crossref","first-page":"305","DOI":"10.1039\/B513270C","author":"Dong","year":"2006","journal-title":"Chem. Commun."},{"key":"su5420_bb3","doi-asserted-by":"crossref","first-page":"2681","DOI":"10.1016\/j.jorganchem.2009.03.017","volume":"694","author":"Felton","year":"2009","journal-title":"J. Organomet. Chem."},{"key":"su5420_bb4","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"su5420_bb5","doi-asserted-by":"crossref","first-page":"9484","DOI":"10.1039\/c0dt00505c","volume":"39","author":"Hu","year":"2010","journal-title":"Dalton Trans."},{"key":"su5420_bb6","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Cryst."},{"key":"su5420_bb7","doi-asserted-by":"crossref","first-page":"3070","DOI":"10.1021\/jo00328a016","volume":"46","author":"Maiolo","year":"1981","journal-title":"J. Org. Chem."},{"key":"su5420_bb8","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/S0969-2126(99)80005-7","volume":"7","author":"Nicolet","year":"1999","journal-title":"Structure"},{"key":"su5420_bb9","doi-asserted-by":"crossref","first-page":"1853","DOI":"10.1126\/science.282.5395.1853","volume":"282","author":"Peters","year":"1998","journal-title":"Science"},{"key":"su5420_bb10","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"su5420_bb11","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"su5420_bb12","doi-asserted-by":"crossref","first-page":"610","DOI":"10.1038\/nature03298","volume":"433","author":"Tard","year":"2005","journal-title":"Nature"},{"key":"su5420_bb13","doi-asserted-by":"crossref","first-page":"2245","DOI":"10.1021\/cr800542q","volume":"109","author":"Tard","year":"2009","journal-title":"Chem. Rev."},{"key":"su5420_bb14","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/03\/00\/su5420\/su5420.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/03\/00\/su5420\/su5420.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:01:14Z","timestamp":1736766074000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989018001731"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,2,13]]},"references-count":14,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2018,3]]}},"alternative-id":["S2056989018001731"],"URL":"https:\/\/doi.org\/10.1107\/s2056989018001731","relation":{},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,2,13]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?su5420","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"16 January 2018","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"29 January 2018","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 February 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?su5420"}},{"value":"\u00a9 2018 Ren and Sang","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}