{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T18:13:34Z","timestamp":1774462414811,"version":"3.50.1"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2018,2,28]],"date-time":"2018-02-28T00:00:00Z","timestamp":1519776000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,2,28]],"date-time":"2018-02-28T00:00:00Z","timestamp":1519776000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,3,1]]},"abstract":"<jats:p>The title compound, sodium chromium\/aluminium molybdenum\/aluminium dodecaoxide, Na<jats:sub>0.72<\/jats:sub>Cr<jats:sub>0.48<\/jats:sub>Al<jats:sub>1.74<\/jats:sub>Mo<jats:sub>2.77<\/jats:sub>O<jats:sub>12<\/jats:sub>, was prepared by solid-state reaction. Its crystal structure is related to NaSICON-type compounds. The framework is built up from<jats:italic>M<\/jats:italic>1O<jats:sub>6<\/jats:sub>(<jats:italic>M<\/jats:italic>1 = Cr\/Al) octahedra and<jats:italic>M<\/jats:italic>2O<jats:sub>4<\/jats:sub>(<jats:italic>M<\/jats:italic>2 = Mo\/Al) tetrahedra interconnected by corners. The three-dimensional framework contains cavities in which sodium cations are located. Two validation models (BVS and CHARDI) were used to confirm the proposed structural model. The mobility of Na<jats:sup>+<\/jats:sup>ions in the structure has been investigated by theoretical means.<\/jats:p>","DOI":"10.1107\/s2056989018003031","type":"journal-article","created":{"date-parts":[[2018,2,28]],"date-time":"2018-02-28T09:57:06Z","timestamp":1519811826000},"page":"406-409","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Elaboration, structural study and validation of a new NASICON-type structure, Na<sub>0.72<\/sub>(Cr<sub>0.48<\/sub>,Al<sub>1.52<\/sub>)(Mo<sub>2.77<\/sub>,Al<sub>0.23<\/sub>)O<sub>12<\/sub>"],"prefix":"10.1107","volume":"74","author":[{"given":"Manel","family":"Sonni","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1056-1963","authenticated-orcid":true,"given":"Imen","family":"Jendoubi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohamed Faouzi","family":"Zid","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,2,28]]},"reference":[{"key":"vn2134_bb1","unstructured":"Adams, S. 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