{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:35Z","timestamp":1740174575105,"version":"3.37.3"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2018,3,2]],"date-time":"2018-03-02T00:00:00Z","timestamp":1519948800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,3,2]],"date-time":"2018-03-02T00:00:00Z","timestamp":1519948800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002322","name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2018,2,27]]},"published-print":{"date-parts":[[2018,4,1]]},"abstract":"<jats:p>The reaction in methanol of Cu<jats:sup>II<\/jats:sup> acetate monohydrate with 5-fluoroisatin 3-oxime deprotonated with KOH in a 1:2 molar ratio and recrystallization from pyridine yielded the title compound, [Cu(C<jats:sub>8<\/jats:sub>H<jats:sub>4<\/jats:sub>FN<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)<jats:sub>2<\/jats:sub>]. In the centrosymmetric complex, the anionic form of the isatin oxime acts as a \u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic> donor, building five-membered metallarings. The Cu<jats:sup>II<\/jats:sup> cation is sixfold coordinated in a slightly distorted octahedral environment by two <jats:italic>trans<\/jats:italic>, equatorial, anionic isatin derivatives and two <jats:italic>trans<\/jats:italic> pyridine ligands in axial positions. The complexes are linked by hydrogen bonding into a three-dimensional network, which is also stabilized by \u03c0\u2013\u03c0 stacking interactions [centroid-to-centroid distance = 3.7352\u2005(9)\u2005\u00c5] and C\u2014H...\u03c0 contacts. The Hirshfeld surface analysis indicates that the major contributions for the crystal packing are H...H (31.80%), H...C (24.30%), H...O (15.20%) and H...F (10.80%). This work is the second report in the literature of a crystal structure of a coordination compound with isatin 3-oxime ligands (coordination chemistry).<\/jats:p>","DOI":"10.1107\/s2056989018003365","type":"journal-article","created":{"date-parts":[[2018,3,2]],"date-time":"2018-03-02T09:21:30Z","timestamp":1519982490000},"page":"428-432","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld analysis of <i>trans<\/i>-bis(5-fluoroindoline-2,3-dione 3-oximato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>\n                  <sup>2<\/sup>,<i>N<\/i>\n                  <sup>3<\/sup>)-<i>trans<\/i>-bis(pyridine-\u03ba<i>N<\/i>)copper(II)"],"prefix":"10.1107","volume":"74","author":[{"given":"Ana Paula Lopes de","family":"Melo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Leandro","family":"Bresolin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bianca Barreto","family":"Martins","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vanessa Carratu","family":"Gervini","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Adriano Bof de","family":"Oliveira","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,3,2]]},"reference":[{"key":"rz5228_bb1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1107\/S0021889804003528","volume":"37","author":"Allen","year":"2004","journal-title":"J. Appl. Cryst."},{"key":"rz5228_bb2","doi-asserted-by":"crossref","first-page":"m790","DOI":"10.1107\/S1600536811018290","volume":"67","author":"Barreto Martins","year":"2011","journal-title":"Acta Cryst. E"},{"key":"rz5228_bb3","unstructured":"Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"rz5228_bb4","unstructured":"Bruker (2014). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"rz5228_bb5","first-page":"355","volume":"3","author":"Erdmann","year":"1841","journal-title":"Ann. Chim. Phys."},{"key":"rz5228_bb6","doi-asserted-by":"crossref","first-page":"257","DOI":"10.1002\/prac.18410220148","volume":"22","author":"Erdmann","year":"1841","journal-title":"J. Prakt. Chem."},{"key":"rz5228_bb7","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"rz5228_bb8","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1007\/BF00549096","volume":"44","author":"Hirshfeld","year":"1977","journal-title":"Theor. Chim. Acta"},{"key":"rz5228_bb9","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"rz5228_bb10","first-page":"371","volume":"3","author":"Laurent","year":"1841","journal-title":"Ann. Chim. Phys."},{"key":"rz5228_bb11","doi-asserted-by":"crossref","first-page":"987","DOI":"10.1107\/S2056989017008301","volume":"73","author":"Martins","year":"2017","journal-title":"Acta Cryst. E"},{"key":"rz5228_bb12","doi-asserted-by":"crossref","first-page":"130","DOI":"10.1080\/14756366.2016.1238366","volume":"32","author":"Meleddu","year":"2017","journal-title":"J. Enzyme Inhib. Med. Chem."},{"key":"rz5228_bb13","doi-asserted-by":"crossref","first-page":"20122","DOI":"10.1038\/srep20122","volume":"6","author":"Mishra","year":"2016","journal-title":"Sci. Rep."},{"key":"rz5228_bb14","unstructured":"SciFinder (2018). Chemical Abstracts Service: Columbus, OH, 2010; RN 58-08-2 (accessed Feb 08, 2018)."},{"key":"rz5228_bb15","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"rz5228_bb16","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"rz5228_bb17","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1021\/cr60109a003","volume":"34","author":"Sumpter","year":"1944","journal-title":"Chem. Rev."},{"key":"rz5228_bb18","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"rz5228_bb19","unstructured":"Wolff, S. K., Grimwood, D. J., McKinnon, J. J., Turner, M. J., Jayatilaka, D. & Spackman, M. A. (2012). CRYSTAL EXPLORER. University of Western Australia, Perth, Australia."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/04\/00\/rz5228\/rz5228.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2018\/04\/00\/rz5228\/rz5228.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:02:24Z","timestamp":1736766144000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989018003365"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,3,2]]},"references-count":19,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2018,4]]}},"alternative-id":["S2056989018003365"],"URL":"https:\/\/doi.org\/10.1107\/s2056989018003365","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989018003365\/rz5228sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989018003365\/rz5228Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2018,3,2]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?rz5228","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 February 2018","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"27 February 2018","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"2 March 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?rz5228"}},{"value":"\u00a9 2018 Melo et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}